1-Aminopyrene

1-Aminopyrene Basic information
Product Name:1-Aminopyrene
Synonyms:3-AMINOPYRENE;1-PYRENAMINE;1-AMINOPYRENE;TIMTEC-BB SBB003375;Pyrene, amino-;pyren-1-ylamine;1-Pyrenamine, 3-Aminopyrene;1-Aminopyrene,97%
CAS:1606-67-3
MF:C16H11N
MW:217.27
EINECS:216-521-3
Product Categories:Pyrenes;Aromatic Hydrocarbons (substituted) & Derivatives
Mol File:1606-67-3.mol
1-Aminopyrene Structure
1-Aminopyrene Chemical Properties
Melting point 115-117 °C (lit.)
Boiling point 347.82°C (rough estimate)
density 1.1227 (rough estimate)
refractive index 1.8230 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Slightly), Methanol (Sparingly)
pka4.32±0.30(Predicted)
form Powder
color Yellow to green
Water Solubility Insoluble in water (0.576 mg/L at 25 deg C).
BRN 1875737
Stability:Stable. Incompatible with strong oxidizing agents.
InChIKeyYZVWKHVRBDQPMQ-UHFFFAOYSA-N
CAS DataBase Reference1606-67-3(CAS DataBase Reference)
NIST Chemistry Reference1-Aminopyrene(1606-67-3)
EPA Substance Registry System1-Pyrenamine (1606-67-3)
Safety Information
Hazard Codes Xn
Risk Statements 22-40-21/22
Safety Statements 45-36/37
WGK Germany 3
RTECS UR2275000
TSCA Yes
HS Code 29214990
Toxicitymouse,LD50,intraperitoneal,250mg/kg (250mg/kg),Archives Internationales de Pharmacodynamie et de Therapie. Vol. 135, Pg. 376, 1962.
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
1-Aminopyrene Usage And Synthesis
Chemical Propertiesyellow-green powder
Uses1-Aminopyrene is used in the synthesis of novel fluorescent nanoscale ionic silicate platelets for use in bacterial detection and other biosensor applications.
UsesIt acts as a precursor molecule for production of other fluorescent probes such as 1-Azidopyrene, APTS, and N-(1-Pyrene)iodoacetamide.
General DescriptionColorless crystals. Yellow needles from hexane, melting point 117-8°C.
Reactivity Profile1-Aminopyrene neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.
Fire Hazard1-Aminopyrene is probably combustible.
Purification Methods1-Aminopyrene [1606-67-3] M 217.3, m 117-118o, pK 1 2.91 (50% aqueous EtOH), pK 2 2.77 (50% aqueous EtOH). Crystallise it from hexane. [Beilstein 12 IV 3460.]
1-Aminopyrene Preparation Products And Raw materials
Raw materialsSodium hydroxide-->Methanol-->Dichloromethane-->Thionyl chloride-->Government regulation-->Ammonia-->Pyridine-->Aluminum chloride-->Acetyl chloride-->Sodium azide-->Sodium hypochlorite-->Pyrene
Preparation ProductsDIRECT BLUE 109
1-amino-8-nitropyrene ACETAMINOPHENOL BP/USP N-(1-PYRENE)IODOACETAMIDE N-(1-PYRENYL)MALEIMIDE EC 2.6.1.2 N-Cyclohexyl-N'-(1-pyrenyl)carbodiimide 4-Amino-benzenesulfonic acid monosodium salt 1,8-DIAMINOPYRENE 6-NITROBENZ(A)PYRENE 6-NITROANTHANTHRENE 3-nitrobenzo(a)pyrene 6-BROMO-1-AMINOPYRENE 1,6-DIAMINOPYRENE 1,3-DINITROPYRENE 1,3,6,8-TETRANITROPYRENE 1-NITROCORONENE 8-ISOTHIOCYANATOPYRENE-1,3,6-TRISULFONIC ACID TRISODIUM SALT 1,3-DIAMINOPYRENE

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