ChemicalBook Product Catalog Organic Chemistry Amides Naphthenic amines derivatives 2,5-DI-TERT-BUTYLANILINE

2,5-DI-TERT-BUTYLANILINE

2,5-DI-TERT-BUTYLANILINE Basic information
Product Name:2,5-DI-TERT-BUTYLANILINE
Synonyms:2,5-DI-TERT-BUTYLANILINE;2,5-Di-tert-butylaniline 99%;2,5-di-tert-butylbenzenamine;Benzenamine, 2,5-bis(1,1-dimethylethyl)-
CAS:21860-03-7
MF:C14H23N
MW:205.34
EINECS:
Product Categories:Amines;C11 to C38;Nitrogen Compounds
Mol File:21860-03-7.mol
2,5-DI-TERT-BUTYLANILINE Structure
2,5-DI-TERT-BUTYLANILINE Chemical Properties
Melting point 103-106 °C (lit.)
BRN 2691916
CAS DataBase Reference21860-03-7
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
2,5-DI-TERT-BUTYLANILINE Usage And Synthesis
Uses2,5-Di-tert-butylaniline has been used in the preparation of:
  • new rigid bidentate nitrogen ligands 1,2-bis[(2,5-di-tert-butylphenyl)imino]acenaphthene (dtb-BIAN)
  • N-(2,5-di-tert-butylphenyl)perylene-3,4-dicarboximide
Purification MethodsThe aniline recrystallises from EtOH in fine needles after steam distillation. It has a pKa2 5 of 3.58 (50% aqueous EtOH). The tosylate has m 164o (from AcOH). [Bell & Wilson J Chem Soc 2340 1956, Carpenter et al. J Org Chem 16 586 1951, Bartlett et al. J Am Chem Soc 76 2349 1954, Beilstein 12 IV 2891.]
2,5-DI-TERT-BUTYLANILINE Preparation Products And Raw materials
Aniline 2,5-DI-TERT-BUTYLANILINE N N'-BIS(2 5-DI-T-BU-PHENYL)-3 4 9 10- 2,5-DI-TERT-BUTYLNITROBENZENE SALOR-INT L165263-1EA 1-(2,5-di-tert-butylphenyl)hydrazine 2,5-DI-TERT-BUTYLPHENYL ISOCYANATE 2,5-ditert-butyl-4-nitroaniline
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