ChemicalBook Product Catalog Chemical Reagents Organic reagents Phosphine ligand (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Basic information
Reaction
Product Name:(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
Synonyms:(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine,min. 97%;(R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-dicyclohexylphos;(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine,min.97%;(r,r)-1-dicyclohexylphosphino-2-[1-(dicyclohexylphosphino)ethyl]ferrocene (acc to cas);(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE;(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE;(R,R)-1-DICYCLOHEXYLPHOSPHINO-2-[1-(DICYCLOHEXYLPHOSPHINO)ETHYL]FERROCENE;JOSIPHOS SL-J003-1
CAS:167416-28-6
MF:C36H50FeP2
MW:600.59
EINECS:
Product Categories:Chiral Phosphine;Ferrocene Series;organophosphine ligand;Josiphos Series
Mol File:167416-28-6.mol
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Structure
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Chemical Properties
alpha -139° ±4° (c 0.5, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color orange
CAS DataBase Reference167416-28-6
Safety Information
Risk Statements 36/37/38
Safety Statements 24/25
WGK Germany 3
F 1-10
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Usage And Synthesis
Reaction
  1. Ligand for Pd-catalyzed C-N cross-coupling
  2. Ligand for Rh-catalyzed C-N cross-coupling
  3. Ligand for Pd-catalyzed asymmetric synthesis of (S)-QUINAP via dynamic kinetic resolution
  4. Ligand for Ni-catalyzed monoarylation of ammonia
Reactions of 167416-28-6
General Descriptionsold in collaboration with Solvias AG
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Preparation Products And Raw materials
(R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-(S)-JOSIPHOS (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE (R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE TRIISOPROPYLPHOSPHINE 1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE 1,3-BIS(DIETHYLPHOSPHINO)PROPANE TRIHEXYLPHOSPHINE (S)-1-[(RP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine 1,3-BIS(DICYCLOHEXYLPHOSPHINO)PROPANE 1,3-BIS(DIMETHYLPHOSPHINO)PROPANE (S,S)-1-DICYCLOHEXYLPHOSPHINO-2-[1-(DICYCLOHEXYLPHOSPHINO)ETHYL]FERROCENE
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