ChemicalBook Product Catalog Chemical Reagents Organic reagents Halogenated aliphatic hydrocarbons 2-Chloroethyl chloroformate

2-Chloroethyl chloroformate

2-Chloroethyl chloroformate Basic information
Product Name:2-Chloroethyl chloroformate
Synonyms:2-chlorethylesterkyselinychlormravenci(czech);2-Chloroethyl chloridocarbonate;2-Chloroethyl chlorocarbonate;beta-chloroethylchlorocarbonate;Carbonochloridicacid,2-chloroethylester;Carbonochloridicacid2-chloroethylester;chlorocarbonicacid2-chloro-ethylester;Chloroformic acid beta-chloroethyl ester
CAS:627-11-2
MF:C3H4Cl2O2
MW:142.97
EINECS:210-982-4
Product Categories:Agrochemicals;CHLOROFORMATES
Mol File:627-11-2.mol
2-Chloroethyl chloroformate Structure
2-Chloroethyl chloroformate Chemical Properties
Melting point <25 °C
Boiling point 155-156°C
density 1.385
vapor pressure 0.23 psi ( 20 °C)
refractive index 1.446
Fp 158°F
storage temp. Inert atmosphere,2-8°C
solubility Ether,Benzene,Acetone[soluble in]
solubility soluble in Ether,Benzene,Acetone
form Liquid
color Colorless to yellow
BRN 506639
InChIKeySVDDJQGVOFZBNX-UHFFFAOYSA-N
CAS DataBase Reference627-11-2(CAS DataBase Reference)
NIST Chemistry ReferenceCarbonochloridic acid, 2-chloroethyl ester(627-11-2)
EPA Substance Registry System2-Chloroethyl chloroformate (627-11-2)
Safety Information
Hazard Codes T
Risk Statements 23-34
Safety Statements 26-36/37/39-45
RIDADR 3277
WGK Germany 3
RTECS LQ5950000
HazardClass 6.1(a)
PackingGroup II
HS Code 29159000
Hazardous Substances Data627-11-2(Hazardous Substances Data)
MSDS Information
ProviderLanguage
2-Chloroethyl chloroformate English
2-Chloroethyl chloroformate Usage And Synthesis
Chemical PropertiesClear colorless liquid
Uses2-Chloroethyl Chloroformate is a reactant used in the preparation of artemisinin-derived dimer carbonates and thiocarbonates with antimalarial activity.
General DescriptionLiquid.
Air & Water ReactionsDecomposed slowly by water forming ethanol, HCl, and CO2; on contact with moist air, 2-Chloroethyl chloroformate gives off HCl fumes; attacks many metals especially in humid atmosphere. REF [Handling Chemicals Safely, 1980. p. 476].
Reactivity Profile2-Chloroethyl chloroformate is an acid halide. Acid halides are water reactive; some are violently reactive. They are incompatible with strong oxidizing agents, alcohols, amines, alkali. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
Health Hazard(Non-Specific -- Ethyl Chloroformate) Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes.
Safety ProfilePoison by inhalation. May also cause fatahties by ingestion or skin contact. May cause burns to the eyes and skin. When heated to decomposition it emits toxic fumes of Cl-
Purification MethodsPurify it by fractional distillation, preferably in a vacuum and store it in a dry atmosphere. [Jones J Chem Soc 2735 1957, Beilstein 3 IV 24.]
2-Chloroethyl chloroformate Preparation Products And Raw materials
Raw materialsHydrochloric acid-->2-Chloroethanol-->Flow Cell
Preparation ProductsVINYL CHLOROFORMATE-->2-Nitro-N-hydroxyethyl aniline-->1,1-Dichloroethane-->2-chloroethyl N-(3-chlorophenyl)carbamate
Dacthal Lurasidone hydrochloride ChloroMethyl Methyl Carbonate Butyl 2-chloroacetate Trioctyl trimellitate Tripropyl orthoformate Cyclopentyl chloroformate Benzyl chloroformate Pentyl chloroformate Cyclohexyl chloroformate 2-Chloroethyl chloroformate 3-CHLOROETHYL CHLOROFORMATE 2,2,2-Trichloroethyl chloroformate (+/-)-1,2,2,2-TETRACHLOROETHYL CHLOROFORMATE AKOS BBS-00004847 1-Chloroethyl chloroformate (JCC),1-CHLOROETHYL CHLOROFORMATE 99%,1-CHLOROETHYL CHLOROFORMATE, 97+%,1-CHLOROETHYL CHLOROFORMATE Ethyl chloroformate 2,2,2-TRICHLORO-1,1-DIMETHYLETHYL CHLOROFORMATE
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