Methyl 2-bromopropionate

Methyl 2-bromopropionate Basic information
Product Name:Methyl 2-bromopropionate
Synonyms:2-Bromopropanoic acid methyl ester;2-bromo-propanoicacimethylester;Methyl alpha-bromopropionate;methyl2-bromopropanoate;Propionic acid, 2-bromo-, methyl ester;DL-a-bromopropionate;DL-2-Methyl broMopropionic;Methyl DL-2-broMopropionate, 99% 100GR
CAS:5445-17-0
MF:C4H7BrO2
MW:167
EINECS:226-642-3
Product Categories:EstersVolatiles/ Semivolatiles;BromoAnalytical Standards;BromoVolatiles/ Semivolatiles;Alpha Sort;Chemical Class;Halogenated;M;MAlphabetic;META - METH;ACID BASED BROMO COMPOUNDS;C2 to C5;Carbonyl Compounds;Esters;Building Blocks;C2 to C5;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;bc0001
Mol File:5445-17-0.mol
Methyl 2-bromopropionate Structure
Methyl 2-bromopropionate Chemical Properties
Melting point 177-180 °C(Solv: water (7732-18-5))
Boiling point 51 °C/19 mmHg (lit.)
density 1.497 g/mL at 25 °C (lit.)
refractive index n20/D 1.451(lit.)
Fp 125 °F
storage temp. Inert atmosphere,2-8°C
solubility water: insoluble
form Liquid
color Clear colorless to slightly yellow
Water Solubility Immiscible
BRN 1720592
InChIKeyACEONLNNWKIPTM-UHFFFAOYSA-N
CAS DataBase Reference5445-17-0(CAS DataBase Reference)
NIST Chemistry ReferencePropanoic acid, 2-bromo-, methyl ester(5445-17-0)
EPA Substance Registry SystemMethyl 2-bromopropionate (5445-17-0)
Safety Information
Hazard Codes C,Xi
Risk Statements 10-34-36/37-36/37/38
Safety Statements 16-26-27-36/37/39-45-37/39
RIDADR UN 2920 8/PG 2
WGK Germany 3
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29159080
MSDS Information
ProviderLanguage
2-Bromopropionic acid methyl ester English
SigmaAldrich English
ACROS English
ALFA English
Methyl 2-bromopropionate Usage And Synthesis
Chemical Propertiesclear colourless to slightly yellow liquid
UsesMethyl 2-bromopropionate was used as initiator during the synthesis of polymer brushes with single-walled carbon nanotubes as backbones. It was used as starting reagent for the synthesis of 2-18F-fluoropropionic acid, positron emission tomography imaging agent for prostate cancer.
Methyl 2-bromopropionate Preparation Products And Raw materials
Preparation ProductsMetalaxyl-->METHYL 2-METHOXYPROPIONATE-->Propanoic acid, 2-[(ethoxythioxomethyl)thio]-, methyl ester-->L-Alanine, N,N-dimethyl-, hydrazide
2-Bromo-4-butanolide 1-BROMO-CYCLOBUTANECARBOXYLIC ACID ETHYL ESTER Ethyl 2-bromovalerate Methyl DALAPON-METHYL ESTER METHYL-2-BROMOPROPIONATE SOLUTION 2000UG/ML IN T-BUTYLMETHYL ETHER 5X1ML Methyl-2-bromopropionate solution METHYL-2-BROMOPROPIONATE, 1000MG, NEAT METHYL 3-BROMOPROPIONATE, (3-BROMOPROPIONIC ACID METHYL ESTER) METHYL-2-BROMOPROPIONATE 1X1ML MTBE 10& Benyl propionic methyl ester Ethyl 2-bromoheptanoate ALPHA-BROMO-GAMMA-VALEROLACTONE 5-BROMO-2.2.5-TRIMETHYL-1.3-DIOXANE-4.6-DIONE METHYL-2-BROMOPROPIONATE,1X1ML, MTBE 100 0UG/ML METHYL-2-BROMOPROPIONATE, [2-14C] Methyl levulinate METHYL THIOPHENE-2-CARBOXYLATE

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