DISULPHUR DECAFLUORIDE

DISULPHUR DECAFLUORIDE Basic information
Product Name:DISULPHUR DECAFLUORIDE
Synonyms:DISULFUR DECAFLUORIDE;DISULPHUR DECAFLUORIDE;Sulfur pentafluoride;Sulfur decafluoride;Einecs 227-204-4;Sulfur fluoride (S2F10);pentafluoruredesoufre;S2F10
CAS:5714-22-7
MF:F10S2
MW:254.11
EINECS:227-204-4
Product Categories:
Mol File:5714-22-7.mol
DISULPHUR DECAFLUORIDE Structure
DISULPHUR DECAFLUORIDE Chemical Properties
Melting point -55°C
Boiling point 29°C
density 2.080
form liquid
Water Solubility insoluble H2O [HAW93]
CAS DataBase Reference5714-22-7
EPA Substance Registry SystemDisulfur decafluoride (5714-22-7)
Safety Information
Hazard Codes T
Risk Statements 26/27/28-34
Safety Statements 26-36/37/39-45
RIDADR 3287
Hazard Note Highly Toxic
HazardClass 6.1(a)
PackingGroup I
Hazardous Substances Data5714-22-7(Hazardous Substances Data)
IDLA1 ppm
MSDS Information
DISULPHUR DECAFLUORIDE Usage And Synthesis
Chemical PropertiesColorless gas; SO2 odor. Insoluble in water.
Chemical PropertiesSulfur pentafluoride is a colorless liquid or gas (above 29°C). Odor like sulfur dioxide. Noncombustible liquid and nonflammable gas.
General DescriptionColorless volatile liquid or gas with an odor like sulfur dioxide. Mp: -92°C; bp: 29°C. Density: 2.08 g cm-3. Insoluble in water. Very toxic by inhalation.
Reactivity ProfileDISULPHUR DECAFLUORIDE is non-combustible. Decomposes when heated above 400°C in air to generate toxic and corrosive fumes of sulfur oxides and sulfur fluorides. Shows little chemical reactivity at room conditions. Acts as a strong oxidizing agent and as a fluorinating agent at elevated temperature as DISULPHUR DECAFLUORIDE begins to break down. Reacts rapidly with molten caustics such as NaOH or KOH.
Health HazardSulfur pentafluoride is a severe pulmonary irritant in animals; severe exposure is expected to cause the same effect in humans.
Safety ProfilePoison by intravenous route. Moderately toxic by inhalation. When heated to decomposition it emits very toxic fumes of Fand SOx. See also FLUORIDES and SULFIDES.
Potential ExposureSulfur pentafluoride is encountered as a by-product in the manufacture of sulfur hexafluoride, which is made by the direct fluorination of sulfur or sulfur dioxide.
SourceProduction by-product of synthesis of sulfur hexafluoride.
ShippingUN3287 Toxic liquids, inorganic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
IncompatibilitiesViolent reaction with many compounds, including reducing agents; chemically active metals; combustible materials, strong acids, alkaline earth sulfides, aluminum carbides, aluminum, amines, calcium sulfide, carbides, chlorine trifluoride, glycerin, hydrides, hydrochloric acid, hydrogen peroxide, hydrogen sulfide, hydroxylamine, magnesium, metal powders, metal sulfides, molybdenum, phenylhydrazine, phosphorous red/friction, phosphorous trichloride, silicon, sulfides, sulfur, sulfur dioxide, sulfur/friction, sulfuric acid, tungsten, hydrogen trisulfide. Fluorides form explosive and toxic gases on contact with strong acids and acid fumes. Reacts with strong caustics. Decomposed in temperatures above 400C forming toxic and corrosive fumes of sulfur oxides and sulfur fluorides; as this chemical decomposes, it acts as both a strong oxidizer and a fluorinating agent.
Waste DisposalReturn refillable compressed gas cylinders to supplier. Nonrefillable cylinders should be disposed of in accordance with local, state and federal regulations. Allow remaining gas to vent slowly into atmosphere in an unconfined area or exhaust hood. Refillable-type cylinders should be returned to original supplier with any valve caps and outlet plugs secured and valve protection caps in place
DISULPHUR DECAFLUORIDE Preparation Products And Raw materials
Preparation ProductsSulfur tetrafluoride
Sulfur hexafluoride Iodine pentafluoride Magnesium oxide DISULPHUR DECAFLUORIDE Sulfur tetrafluoride

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