Dinocap

Dinocap Basic information
Product Name:Dinocap
Synonyms:KARATHAN;KARATHANE;KARATHANE(R);ISOCOTHANE(R);DINOCAP;CROTOTHANE;CROTOTHANE(R);CR1639(R)
CAS:39300-45-3
MF:C18H24N2O6
MW:364.39
EINECS:254-408-0
Product Categories:Dinitrophenol compounds;AcaricidesPesticides&Metabolites;Alpha sort;D;DAlphabetic;DID - DINPesticides;Fungicides;Pesticides;Pesticides&Metabolites
Mol File:39300-45-3.mol
Dinocap Structure
Dinocap Chemical Properties
Boiling point 138-140°C
density 1.10
refractive index 1.5700 (estimate)
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
Water Solubility practically insoluble
Merck 13,3316
CAS DataBase Reference39300-45-3(CAS DataBase Reference)
EPA Substance Registry SystemDinocap (39300-45-3)
Safety Information
Hazard Codes T;N,N,T
Risk Statements 61-20/22-38-43-48/22-50/53-22-20
Safety Statements 53-45-60-61
RIDADR UN 3082
RTECS GQ5775000
HazardClass 6.1(a)
PackingGroup I
HS Code 29161900
Hazardous Substances Data39300-45-3(Hazardous Substances Data)
ToxicityLD50 in male rats (mg/kg): 23 i.v.; 980 orally (Larson)
MSDS Information
Dinocap Usage And Synthesis
DescriptionDinocap is shown in both the 2,4-dinitro and 2,6-dinitro configurations with 1-methylheptyl and 1-ethylhexyl chains, respectively, but may also have a 1-propylpentyl configuration for the “octyl” chain. It is a dark brown liquid with a bp = 138 to 140 ?C, vp = 5.3×10?6 mPa, a Kow LogP = 4.54, and is almost insoluble (<0.1 mgL?1) in water (5).
UsesAcaricide; fungicide.
DefinitionChEBI: 2,4-dinitro-6-(octan-2-yl)phenyl (E)-but-2-enoate is an enoate ester obtained by formal condensation of the carboxy group of 3-methylacrylic acid with the phenolic hydroxy group of 2,4-dinitro-6-(octan-2-yl)phenol. It is a C-nitro compound and an enoate ester.
General DescriptionDark oily liquid. Nearly insoluble in water. Used as a fungicide and acaricide.
Air & Water ReactionsNearly insoluble in water. Hydrolysis of the ester group occurs with alkaline pHs.
Reactivity ProfileA dinitrophenyl derivative.
Agricultural UsesFungicide, Acaricide: Dinocap is a foliar fungicide/miticide used to control powdery mildew. It is applied to limit mites in apples and grapes crops outside the U.S., mainly in Europe, the Middle East and northern Africa. It is also used to control powdery mildew on fruit, vegetables and ornamentals. DAS, the registrant of dinocap, intends to support tolerances for dinocap residues in/on apples and grapes to permit legal importation of these commodities into the U.S. Not approved for use in EU countries. Not currently registered in the U.S. There are 17 global suppliers.
Trade nameACTUAL DINOCAP®; ARATHANE®; CAPRANE®; CR 1639®; CEKUCAP® 25 WP; CROTOTHANE®; DICAP®; DIKAR®; EZENOAN®; ISCOTHANE®; ISOCOTHANE®; KARATHANE®[C]; KARATHANE® WD[C]; KARATHENE®[C]; MILDANE®; MILDEX®
Safety ProfilePoison by ingestion and intravenous routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Questionable carcinogen with experimental neoplastigenic data. See NITRATES. When heated to decomposition it emits toxic fumes of NOx.
Toxicity evaluationDinocap shows moderate acute toxicity to mammals (acute oral LD50 in rats of 1,000 to 5,000 mg/kg) with moderate dermal irritation but substantial eye irritation in rabbits (Rohm & Haas MSDS C&P MSDS reference listing; MDL MSDS database listing). Dinocap is teratogenic to mice and hamsters at 10 to 100 mg/kg/day (48–51), although no evidence of teratogenic effects were seen in rabbits (Rohm & Haas MSDS C&P MSDS reference listing). Dinocap is classified as “toxic” to fish but is listed as “nontoxic” to bees (52).
Dinocap Preparation Products And Raw materials
Chlorothalonil Polyoxyethylene octylphenol ether Polybutene DINOCAP SOLUTION 100UG/ML IN METHANOL 5X1ML Dinocap Maleic acid Maleic anhydride DINOCAP SOLUTION 100UG/ML IN METHANOL 5ML Tris(trimethylsilyl)phosphate DINOCAP (RING-13C6) Fumaric acid Triton X-100 4-tert-Octylphenol 3-BUTENE-1,2-DIOL DINOCAP SOLUTION 100UG/ML IN METHANOL 1ML 2-(1-METHYLHEPTYL)-4,6-DINITROPHENYL CROTONATE,2-METHYLHEPTYL-4,6-DINITROPHENYL CROTONATE Mancozeb-dinocap mixture DINOCAP (RING-13C6) SOLUTION 100UG/ML IN N-NONANE 1.2ML

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