Rum Ether

Rum Ether Basic information
Product Name:Rum Ether
Synonyms:RUM ETHER;ETHYL OXYHYDRATE;FEMA 2996;Pyroligneousacids,reactionproductswithEtalc.,distillates;pyroligneousacids,reactionproductswithethylalc,distillates;zv8-253;RUM ETHER, NATURAL;Ethyl formaceto
CAS:8030-89-5
MF:C2 H6 O.unspecified
MW:0
EINECS:232-449-5
Product Categories:
Mol File:Mol File
Rum Ether Structure
Rum Ether Chemical Properties
Boiling point 76 °C(lit.)
density 0.825 g/mL at 25 °C(lit.)
FEMA 2996 | RUM ETHER
refractive index n20/D 1.366(lit.)
Fp 42 °F
Odorat 1.00 % in propylene glycol. acidic woody burnt meaty whiskey
Odor Typeburnt
CAS DataBase Reference8030-89-5
EPA Substance Registry SystemPyroligneous acids, reaction products with Et alc., distillates (8030-89-5)
Safety Information
Hazard Codes F
Risk Statements 10-11
Safety Statements 16
RIDADR UN 1993 3/PG 2
WGK Germany 2
RTECS LB8450000
Hazardous Substances Data8030-89-5(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
Rum Ether Usage And Synthesis
Chemical PropertiesColorless liquid; sharp rum-like odor. Miscible in alcohol, glycerin, propylene glycol.
Chemical PropertiesRum ether has a rum-like odor and flavor. A gas chromatographic analysis of rum ether has led to the identification of 22 components in varying concentrations (as low as 50 ppm); caramel is added to the rum ether for coloring purposes; in general, the addition of rum ether to the finished liquor does not exceed 2 to 3% for flavoring purposes. For a detailed description of this compound, refer to Burdock (1997).
UsesRum Ether is a synthetic flavoring agent that is a stable, colorless to yellow liquid of ethereal rum-like note. it should be stored in glass and stainless steel containers. it is used to intensify rum flavors for application in beverages, candy, and ice cream at 67–320 ppm and in alcoholic beverages at 1,600 ppm. it is also termed ethyl oxyhydrate.
UsesFood additive.
PreparationPlace 95% ethanol and manganese dioxide in the reaction flask equipped with distillation apparatus; add pyroligneous acid and finally sulfuric acid (66°Be) slowly with agitation, maintaining the final temperature below 40 to 50°C; the mixture is then distilled under atmospheric pressure and the fraction distilling between 60 and 100°C is collected; finally, the collected fraction undergoes rectification; the rectified fraction exhibits a boiling range between 65 and 98°C; average yield is 98% based on the amount of ethanol used. Sometimes the distillate is further divided into two additional fractions—one more, and one less rich in acetaldehyde; the amount of starting material employed varies between the following limits: ethanol (95%) 12 to 25 kg, pyroligneous acid (12% acetic acid) 10 to 16 kg, sulfuric acid (66°Be) 3 to 8 kg, manganese dioxide 2 to 5 kg.
DefinitionThe distillate from the reaction products of the aqueous distillate from the destructive distillation of wood and ethyl alcohol.
Taste threshold valuesTaste characteristics at 50 ppm: burnt, smoky, woody, caramellic with rum and brandy notes.
Rum Ether Preparation Products And Raw materials
Raw materialsManganese dioxide-->PYROLIGNEOUS ACID
Aluminum acetylacetonate Rum Ether N-BUTYLISOCYANIDE PHENYLSELENOL C8E3 DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) Ethylbenzene 2,4-PENTANEDIONE, SILVER DERIVATIVE 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE COBALT(II) ACETYLACETONATE Cupric acetylacetonate Diethyl ether Ethyl isocyanoacetate TERT-BUTYL ISOCYANIDE Ferric acetylacetonate COBALT ETHYLENE DIAMINE CHLORIDE Benzyl isocyanide Dimethyl ether

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