1,2-NAPHTHOQUINONE-4-SULFONIC ACID SODIUM SALT

1,2-NAPHTHOQUINONE-4-SULFONIC ACID SODIUM SALT Basic information
Product Name:1,2-NAPHTHOQUINONE-4-SULFONIC ACID SODIUM SALT
Synonyms:MANCHESTER BLUE;1,2-NAPTHOQUINONE-4-SULFONIC ACID NA SALT;1,2-NAPHTHAQUINONE-4-SULPHONIC ACID SODIUM SALT;1,2-NAPHTHOQUINONE-4-SULFONIC ACID;1,2-NAPHTHOQUINONE-4-SULFONIC ACID SODIUM SALT;1,2-NAPHTHOQUINONE-4-SULPHONIC ACID SODIUM SALT;3,4-DIHYDRO-3,4-DIOXO-1-NAPHTHALENESULFONIC ACID SODIUM SALT;BETA-NAPHTHOQUINONE-4-SULFONIC ACID SODIUM SALT
CAS:521-24-4
MF:C10H5NaO5S
MW:260.2
EINECS:208-308-9
Product Categories:Building Blocks;Chemical Synthesis;Intermediates of Dyes and Pigments;Organic Building Blocks;Sulfonic/Sulfinic Acids;Sulfur Compounds
Mol File:521-24-4.mol
1,2-NAPHTHOQUINONE-4-SULFONIC ACID SODIUM SALT Structure
1,2-NAPHTHOQUINONE-4-SULFONIC ACID SODIUM SALT Chemical Properties
Melting point 289 °C (dec.)(lit.)
storage temp. 2-8°C
solubility H2O: 50 mg/mL, clear
form solid
color dark orange
OdorOdorless
Water Solubility Soluble in water and acetone. Slightly soluble in alcohol and ethanol. Insoluble in chloroform.
Merck 14,8646
BRN 4169788
Stability:Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference521-24-4(CAS DataBase Reference)
EPA Substance Registry System1,2-Naphthoquinone-4-sulfonic acid sodium salt (521-24-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
RTECS QK1490000
TSCA Yes
HS Code 29147000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
1,2-NAPHTHOQUINONE-4-SULFONIC ACID SODIUM SALT Usage And Synthesis
Chemical Propertiespowder
Uses1,2-Naphthoquinone-4-sulfonic acid sodium salt is used in the characterization of phanerochaete chrysosporium. Used in the synthesis of carbohydrate based napthoquinones as anticancer agents.
UsesColorimetric determination of amino acids and amines.
UsesColorimetric determination of amino acids and amines1,2-Naphthoquinone-4-sulfonic acid sodium salt is used for the colorimetric determination of amino acids, amines and procaine hydrochloride in pharmaceutical preparations. It is also used in the characterization of phanerochaete chrysosporium. Further, it acts as an intermediate in the synthesis of carbohydrate based napthoquinones, which acts as anticancer agents.
Purification MethodsIt forms yellow crystals from aqueous EtOH and should be dried at 80o in vacuo. Its solubility in H2O is 5% [Martin & Fieser Org Synth Coll Vol III 633 1955, Danielson J Biol Chem 101 507 1933, UV: Rosenblatt et al. Anal Chem 27 1290 1955]. [Beilstein 11 IV 668.]
1,2-NAPHTHOQUINONE-4-SULFONIC ACID SODIUM SALT Preparation Products And Raw materials
Methyl allyl ketone 1-Phenyl-1,2-propanedione Benzeneacetaldehyde, 2-methyl- (9CI) Sodium hydride Methylglyoxal ETHANESULFONIC ACID SODIUM SALT PHENYLGLYOXAL MONOHYDRATE Phenylacetone 1-ETHYL-2-VINYL-BENZENE 2,3-Butanedione ETHYL-O-TOLYL KETONE ETHANESULFONIC ACID SODIUM SALT MONO- Sodium methanesulfinate 4-Phenyl-1-butene 2-METHYLSTYRENE Sodium hydroxide 1,2-NAPHTHOQUINONE Ethylenesulfonic acid

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