Cyclopropyl phenyl ketone

Cyclopropyl phenyl ketone Basic information
Product Name:Cyclopropyl phenyl ketone
Synonyms:Methanone,cyclopropylphenyl-;BENZOYLCYCLOPROPANE;CYCLOPROPYL PHENYL KETONE;CYCLOPROPYL-PHENYL-METHANONE;Cyclopropylphenylketone,97%;Cyclopropyl phenyl k;Cyclopropyl phenyl ketone 98%;Ketone, cyclopropyl phenyl
CAS:3481-02-5
MF:C10H10O
MW:146.19
EINECS:222-458-2
Product Categories:Cyclopropanes;Simple 3-Membered Ring Compounds
Mol File:3481-02-5.mol
Cyclopropyl phenyl ketone Structure
Cyclopropyl phenyl ketone Chemical Properties
Melting point 7-9 °C(lit.)
Boiling point 121-123 °C15 mm Hg(lit.)
density 1.058 g/mL at 25 °C(lit.)
vapor density 5 (vs air)
refractive index n20/D 1.553(lit.)
Fp 195 °F
storage temp. Sealed in dry,2-8°C
form clear liquid
color Colorless to Light yellow
Water Solubility Insoluble in water.
BRN 1860145
CAS DataBase Reference3481-02-5(CAS DataBase Reference)
NIST Chemistry ReferenceCyclopropyl phenyl ketone(3481-02-5)
Safety Information
Safety Statements 23-24/25
WGK Germany 3
HS Code 2914390090
MSDS Information
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Cyclopropyl phenyl ketone Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS TO LIGHT YELLOW LIQUID
UsesCyclopropyl phenyl ketone was used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It was used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
UsesCyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
Synthesis Reference(s)The Journal of Organic Chemistry, 45, p. 2921, 1980 DOI: 10.1021/jo01302a038
Tetrahedron Letters, 16, p. 4389, 1975 DOI: 10.1016/S0040-4039(00)91132-8
1,3-Diphenylacetone Cyclopropyl phenyl ketone Cyclopropyl methyl ketone Cyclopropyl 4-methoxyphenyl ketone 1-CHLORO-3,3-DIMETHYLBUTANE PHENYL RESIN Phenylacetone Cyclopropyl-(2,4-dimethylphenyl)methanone CYCLOPROPYL 4-ETHYLPHENYL KETONE CYCLOPROPYLBENZENE 4-Methoxyphenylacetone DIMETHYLGLYOXIME DISODIUM SALT PHENYL VALERATE 4-CHLORO-3-NITROPHENYL CYCLOPROPYL KETONE Dicyclopropane methylamine 4-tert-Butylphenyl cyclopropyl ketone Cyclopropyl-(3,4-dimethylphenyl)methanone cyclopropyl p-tolyl ketone

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