2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE

2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE Basic information
Product Name:2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE
Synonyms:2-(CHLOROMETHYL)-3-(TRICHLOROSILYL)PROPENE;2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE;TRICHLORO[2-(CHLOROMETHYL)ALLYL]SILANE;trichloro-[2-(chloromethyl)prop-2-enyl]silane;Trichloro[2-(chloromethyl)allyl]silane 98%;richloro-[2-(chloromethyl)prop-2-enyl]silane;Trichloro[2-(chloromethyl)-2-propen-1-yl]silane;Silane, trichloro[2-(chloromethyl)-2-propen-1-yl]-
CAS:18147-84-7
MF:C4H6Cl4Si
MW:223.99
EINECS:
Product Categories:POSS? Precursors and Intermediates;RSiCl3Self Assembly&Contact Printing;Self-Assembly Materials;Silanes;Silsesquioxanes: POSS? Nanohybrids
Mol File:18147-84-7.mol
2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE Structure
2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE Chemical Properties
Boiling point 31 °C0.1 mm Hg(lit.)
density 1.346 g/mL at 25 °C(lit.)
refractive index n20/D 1.484(lit.)
Fp 181 °F
Specific Gravity1.3473
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Safety Information
Hazard Codes C
Risk Statements 14-34
Safety Statements 26-27-36/37/39-45
RIDADR UN 2987 8/PG 2
WGK Germany 3
TSCA No
MSDS Information
ProviderLanguage
SigmaAldrich English
2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE Usage And Synthesis
UsesTrichloro[2-(chloromethyl)-2-propen-1-yl]silane is an intermediate used in the synthesis of 2-?(Chloromethyl)?allyl-?trimethylsilane (C371430), which is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-?(Chloromethyl)?allyl-?trimethylsilane was used in catalytic Sakurai reaction of α,?β-?enones.
2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE Preparation Products And Raw materials
Methacryloyl chloride 1-Methylcyclopropene Isobutylene METHYLSTYRENE ALLYLDICHLOROSILANE 2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE 3-Chloropropyltrichlorosilane 2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE PROPYLENE ALLYLTRICHLOROSILANE 3-Chloro-2-methylpropene

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