DIHYDRO CUMINYL ALCOHOL

DIHYDRO CUMINYL ALCOHOL Basic information
Product Name:DIHYDRO CUMINYL ALCOHOL
Synonyms:DIHYDRO CUMINYL ALCOHOL;Perilla alcohol Dihydrocuminyl alcohol;(4-Isopropenyl-1-cyclohexen-1-yl)methanol;1,8-p-Menthadien-7-ol;1-perillalcohol;4-(1-methylethenyl)-1-cyclohexene-1-methano;(4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)Methanol;1-HYDROXYMETHYL-4-(1-METHYLVINYL)-CYCLOHEXENE
CAS:536-59-4
MF:C10H16O
MW:152.23
EINECS:208-639-9
Product Categories:Benzhydrols, Benzyl & Special Alcohols;Furans ,Coumarins
Mol File:536-59-4.mol
DIHYDRO CUMINYL ALCOHOL Structure
DIHYDRO CUMINYL ALCOHOL Chemical Properties
Melting point 271-272 °C
Boiling point 119-121 °C11 mm Hg(lit.)
density 0.96 g/mL at 25 °C(lit.)
FEMA 2664 | P-MENTHA-1,8-DIEN-7-OL
refractive index n20/D 1.501(lit.)
Fp >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka14.85±0.10(Predicted)
Odorat 100.00 %. green cumin spicy aromatic woody cardamom floral waxy violet
Odor Typegreen
JECFA Number974
LogP3.170
CAS DataBase Reference536-59-4
EPA Substance Registry System1-Cyclohexene-1-methanol, 4-(1-methylethenyl)- (536-59-4)
Safety Information
Hazard Codes Xi
Risk Statements 37/38-41-36/37/38
Safety Statements 26-39-36
WGK Germany 3
RTECS OS8395000
HS Code 29061990
ToxicityLD50 orl-rat: 2100 mg/kg FCTXAV 19,253,81
MSDS Information
DIHYDRO CUMINYL ALCOHOL Usage And Synthesis
Descriptionp-Mentha-1,8-dien-7-ol has a characteristic odor similar to linalool and terpineol. The L-form is obtained starting from (3-pinene or by reducing perillic aldehyde with zinc dust and acetic acid, followed by saponification of the acetate.
Chemical Propertiesp-Mentha-1,8-dien-7-ol has a characteristic odor similar to linalool and terpineol.
Chemical Propertiesclear colorless to light yellow liquid
OccurrenceThe d- and l-forms occur naturally in gingergrass essential oil; the l-form is found in lavandin and bergamot, while the d-form is found in caraway; also reported found in the essential oils of Juniperus sabina L. and East Indian geranium. Also reported found in citrus peel oils, berries, peppermint oil, Scotch peppermint oil, hop oil, cardamom, laurel, lemon balm, lamb’s let tuce, mastic gum oil and bullock’s head (Annona reticulata).
Uses(4-(Prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol is used in preparation of perilla alcohol leaf alcohol carbonate as perfume.
Usesantineoplastic, apoptosis inducer; skin irritant, LD50(rat) 2100 mg/kg po
DefinitionChEBI: A limonene monoterpenoid consists of a cyclohexene ring substituted by a hydroxymethyl and a prop-1-en-2-yl group at positions 1 and 4 respectively. It is a constituent of a variety of essential oils including lavender.
PreparationThe l-form is obtained starting from β-pinene or by reducing perillic aldehyde with zinc dust and acetic acid, followed by saponification of the acetate.
Aroma threshold valuesDetection: 7 ppm
Safety ProfileModerately toxic by ingestion. A severe skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
RARECHEM AL BP 1461 RARECHEM AL BP 0003 DIHYDRO CUMINYL ALCOHOL METHYL PERILLATE RARECHEM AQ BC 9125 [R,S] PERILLYL ALCOHOL [1-3H] 7-Hydroxy Cannabidiol DIHYDRO CUMINYL ACETATE PERILLIC ACID RARECHEM AL BO 2084 (+)-PERILLYL ALCOHOL RARECHEM AQ BC 9020 RARECHEM AQ BC 9101 7-Hydroxy Cannabidiol-d3 RARECHEM AL BO 2062 4a-Hydroxyavermectin B1 (1R,3R,4R,4aR,6R)-4,4a-dimethyl-6-prop-1-en-2-yl-2,3,4,5,6,7-hexahydro-1H-naphthalene-1,3-diol (-)-PERILLYL ALCOHOL

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