Tetrabutylammonium tribromide

Tetrabutylammonium tribromide Basic information
Product Name:Tetrabutylammonium tribromide
Synonyms:Tetrabutylammonium perbromide;Tetra-n-butylammonium tribromide, 98+%;TBABr3, Tetrabutylammonium bromide perbromide;Tetrabutylammonium tribromide ,98%;Tetra-n-butylammonium Tribromide(TBAB);TETRA-N-BUTYLAMMONUIM TRIBROMIDE;TETRABUTYLAMMONIUM BROMIDE PERBROMIDE (TRIBROMIDE);Tetrabutylammonium t
CAS:38932-80-8
MF:C16H36Br3N-2
MW:482.18
EINECS:609-598-3
Product Categories:Ammonium Polyhalides, etc. (Quaternary);Bromination;Halogenation;Quaternary Ammonium Compounds;Synthetic Organic Chemistry;Ammonium;Ammonium Salts;Chemical Synthesis;Ionic Liquids;Phase Transfer Catalysts;Specialty Synthesis;Synthetic Reagents;bc0001
Mol File:38932-80-8.mol
Tetrabutylammonium tribromide Structure
Tetrabutylammonium tribromide Chemical Properties
Melting point 71-76 °C (lit.)
density 1.5469 (rough estimate)
refractive index 1.6500 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Acetone (Slightly), Chloroform (Slightly)
form Crystalline Powder
color Yellow
Water Solubility insoluble
BRN 3746114
InChIKeyKEWPQWXPEDFWRU-UHFFFAOYSA-N
CAS DataBase Reference38932-80-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
RIDADR UN3261
WGK Germany 3
HazardClass 8
PackingGroup III
HS Code 29211990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Tetrabutylammonium tribromide Usage And Synthesis
Chemical Propertiesorange crystalline powder
Uses
  1. Tetrabutylammonium tribromide (TBATB) is a salt of the lipophilic tetrabutylammonium cation and the linear tribromide anion. It is used as a phase transfer catalyst in organic synthesis as well as a mild brominating agent. A wide range of O-isopropylidene derivatives can be prepared from the sugars and their derivatives on reaction with acetone at room temperature by employing 2 mol % of tetrabutylammonium tribromide as a catalyst. Good yields, low catalyst loading, mild reaction conditions, and a non-aqueous workup procedure are some major advantages of this protocol.
  2. Tetrabutylammonium tribromide as an efficient generator of HBr for an efficient chemoselective reagent for acetalization of carbonyl compounds.
    Tetrabutylammonium Tribromide (TBATB) as An Efficient Generator of HBr for an Efficient Chemoselective Reagent for Acetalization of Carbonyl Compounds
  3. It is sometimes used as a reagent used in organic synthesis as a conveniently weighable, solid source of bromine.
  4. Tetra-n-butylammonium tribromide is useful for the preparation of vicinal dibromides from alkenes and alkynes and alfa-bromo acetals.
  5. it is utilized to generate hydrogen bromide, which is used as an efficient chemoselective reagent for acetalization of carbonyl compounds.
UsesTetrabutylammonium Tribromide is used in the synthesis of antimicrobial agents via chalcones. Also used in the synthesis of potent tubulin polymerization inhibitors.
Tetrabutylammonium tribromide Preparation Products And Raw materials
Preparation Products4-(4-CHLOROPHENYL)-1,2,3-THIADIAZOL-5-AMINE-->3,5-diisopropylphenol-->4-[4-(TRIFLUOROMETHYL)PHENYL]-1,2,3-THIADIAZOL-5-AMINE-->1-Bromopinacolone
Tetrabutylammonium hydrogen carbonate Tetrabutylammonium azide Tetrabutylurea Tetraethyl orthocarbonate Tetrabutylammonium chloride monohydrate Cinnolino[5,4,3-cde]cinnoline TETRABUTYLAMMONIUM FLUORIDE Tetrabutylammonium triflate TERT-BUTYL DIAZOACETATE TETRABUTYLPHOSPHONIUM TETRAFLUOROBORATE Tetrabutylammonium Difluorotriphenylsilicate Tetramethylammonium tribromide DIMETHYL DIETHYL AMMONIUM BROMIDE ETHYL-BIS-(SODIUMTETRAZOYLAZO)ACETATE butyltripropylammonium bromide TETRABUTYL AMMONIUM BROMIDE Methyltripropyl ammonium bromide Triethylmethylammonium bromide

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