Nickel sulfide

Nickel sulfide Basic information
Product Name:Nickel sulfide
Synonyms:nickeltritadisulphide[qr];trinickeldisulfide;trinickeldisulphide;Nickel subsulfide (as Ni)(trinickel disulfide) total dust;Nickel sulphide roasting (fumes & dust) (as Ni) (also see metal);nickel subsulphide trinickel disulphide;Nickel sulfide, 99.9% trace metals basis;Heazlewoodite
CAS:12035-72-2
MF:Ni3S2
MW:240.21
EINECS:234-829-6
Product Categories:Inorganics
Mol File:12035-72-2.mol
Nickel sulfide Structure
Nickel sulfide Chemical Properties
Melting point 797℃
density 5.8 g/mL at 25 °C(lit.)
form Powder
color Black
Water Solubility Soluble in water(0,00735 g/L at 20°C).
Exposure limitsACGIH: TWA 0.1 mg/m3; TWA 0.2 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference12035-72-2
EPA Substance Registry SystemNickel subsulfide (12035-72-2)
Safety Information
Hazard Codes T,N
Risk Statements 49-43-51/53-68-50/53-48/23-20
Safety Statements 53-45-61-60
RIDADR UN 3077 9/PG 3
WGK Germany 2
RTECS QR9800000
TSCA Yes
HazardClass 9
PackingGroup III
HS Code 28309090
Hazardous Substances Data12035-72-2(Hazardous Substances Data)
MSDS Information
Nickel sulfide Usage And Synthesis
Chemical Propertiesyellowish; naturally occurring nickel mineral [KIR81] [CRC10]
UsesNickel subsulfide is used as a catalyst in refining crude oil containing a considerable amount of sulfur.
UsesNickel sulfide was implanted in mice, to induce the growth of malignant fibrous histiocytomas.
Production MethodsNickel subsulfide can be prepared by a direct reaction between nickel and sulfur at a temperature over 300C. This process makes it possible to prepare the purest preparation in the form of a brittle melt or monocrystals. The largest industrial source of nickel subsulfide is the metallurgic process of nickel matte smelting. Nickel matte consists of nickel subsulfide and some quantities of iron and copper sulfides. It is an intermediate product in nickel metallurgy regardless of the type of the processed ores.
General DescriptionPale yellowish-bronze metallic-lustrous crystals or shiny gold-green (metallic) crystalline powder.
Air & Water ReactionsNICKEL SULFIDE -150 MESH 99.7% is sensitive to prolonged exposure to air. Insoluble in water.
Reactivity ProfileInorganic sulfides, such as NICKEL SULFIDE -150 MESH 99.7%, are generally basic and therefore incompatible with acids. Many of these compounds are reducing agents and therefore react vigorously with oxidizing agents, including inorganic oxoacids, organic peroxides and epoxides. Simple salts of sulfides (such as sodium, potassium, and ammonium sulfide) react vigorously with acids to release hydrogen sulfide gas.
Fire HazardFlash point data for NICKEL SULFIDE -150 MESH 99.7% are not available. NICKEL SULFIDE -150 MESH 99.7% is probably combustible.
Flammability and ExplosibilityNonflammable
Safety ProfileConfirmed carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic, and teratogenic data. Poison by intraperitoneal and intratracheal routes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of SOx. See also NICKEL COhlPOUNDS and SULFIDES.
Nickel sulfide Preparation Products And Raw materials
Tin sulfide Gallium(III) oxide Zinc sulfide MOLYBDENUM SELENIDE LEAD TELLURIDE INDIUM(I) CHLORIDE Nickel(II) oxide Diantimony trioxide INDIUM(I) IODIDE INDIUM TELLURIDE Gallium arsenide ANTIMONY(III) IODIDE LEAD SESQUIOXIDE NICKEL SULFIDE Nickel sulfide, #150 mesh, 99.7% metals basis NICKEL SULFIDE Nickel NICKEL SULFIDE

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