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Dibenzyl azodicarboxylate

Dibenzyl azodicarboxylate Basic information
Product Name:Dibenzyl azodicarboxylate
Synonyms:diazenedicarboxylicacid,bis(phenylmethyl)ester;Phenylmethyl N-(phenylmethoxycarbonylimino)carbamate;Dibenzyl Azodicarboxylate (40% in Dichloromethane, ca. 1.7mol/L);Azobis(formic acid benzyl) ester;Azodiformic acid dibenzyl ester;Bis(benzyloxycarbonyl)diazene;Diazene-1,2-dicarboxylic acid dibenzyl ester;Diazenedicarboxylic acid dibenzyl ester
CAS:2449-05-0
MF:C16H14N2O4
MW:298.29
EINECS:219-508-0
Product Categories:Aromatic Esters;Azo/Diazo Compounds;Nitrogen Compounds;Organic Building Blocks
Mol File:2449-05-0.mol
Dibenzyl azodicarboxylate Structure
Dibenzyl azodicarboxylate Chemical Properties
Melting point 43-47 °C (lit.)
Boiling point 439.72°C (rough estimate)
density 1.2028 (rough estimate)
refractive index 1.6240 (estimate)
Fp >230 °F
storage temp. 2-8°C
form Crystalline Powder
color Yellow to orange
Sensitive Light Sensitive
BRN 2298734
InChIKeyIRJKSAIGIYODAN-ISLYRVAYSA-N
CAS DataBase Reference2449-05-0(CAS DataBase Reference)
EPA Substance Registry SystemDiazenedicarboxylic acid, bis(phenylmethyl) ester (2449-05-0)
Safety Information
Hazard Codes Xi,F
Risk Statements 36/37/38-11
Safety Statements 26-37/39-16
RIDADR 3224
WGK Germany 3
TSCA Yes
HS Code 29270000
MSDS Information
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Dibenzyl azodicarboxylate Usage And Synthesis
Chemical Propertiesyellow to orange crystalline powder
UsesDibenzyl azodicarboxylate was used as electrophilic reagent in the synthesis of C-glycosyl α-amino acids via proline-catalyzed α-amination of C-glycosylalkyl aldehydes. It was used in enantioselective synthesis of optically active pyrazolidine derivatives.
UsesDibenzyl azodicarboxylate is a reagent used in the synthesis of Minocycline-d6 (M344797). Minocycline-d6 is a labeled second generation tetracycline antibiotic. Antibacterial.
General DescriptionDibenzyl azodicarboxylate undergoes[4+2] cycloaddition reaction with glycal to yield 2-aminoglycosides.
Dibenzyl azodicarboxylate Preparation Products And Raw materials
Raw materials1,2-DICARBOBENZYLOXYHYDRAZINE
Palladium (II) Acetate N,N,N',N'-Tetramethylazodicarboxamide Sodium acetate trihydrate AZODICARBOXYLIC BISMORPHOLIDE Benzophenone Diethyl azodicarboxylate Di-tert-Butyl azodicarboxylate Sodium tert-butoxide 1,1'-(Azodicarbonyl)-dipiperidine Diisopropyl azodicarboxylate Dibenzyl azodicarboxylate Bis(4-chlorobenzyl) azodicarboxylate Benzylparaben Dibenzyl phosphate Carbobenzoxyhydrazide AZODICARBOXYLIC ACID DIMETHYL ESTER Benzyl chloroformate Benzyl benzoate
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