2-tert-Butyl-1,4-benzoquinone

2-tert-Butyl-1,4-benzoquinone Basic information
Product Name:2-tert-Butyl-1,4-benzoquinone
Synonyms:2-TERT-BUTYL-1,4-BENZOQUINONE;2-TERT-BUTYLQUINONE;2-TERT-BUTYL-P-QUINONE;2-(1,1-dimethylethyl)-2,5-cyclohexadien-1,4-dione;2,5-Cyclohexadiene-1,4-dione,2-(1,1-dimethylethyl)-;2-TERT-BUTYL(1,4)PARAQUINONE;PARA-BENZOQUINONE,2-TERT-BUTYL-;2-TERT-BUTYL-1,4-QUINONE
CAS:3602-55-9
MF:C10H12O2
MW:164.2
EINECS:222-757-8
Product Categories:C10;Carbonyl Compounds;Benzoquinones;Ketones
Mol File:3602-55-9.mol
2-tert-Butyl-1,4-benzoquinone Structure
2-tert-Butyl-1,4-benzoquinone Chemical Properties
Melting point 54-58 °C(lit.)
Boiling point 227.8±15.0 °C(Predicted)
density 1.092±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform, Methanol (Slightly)
form Solid
color Dark Yellow
CAS DataBase Reference3602-55-9(CAS DataBase Reference)
NIST Chemistry Reference2,5-Cyclohexadiene-1,4-dione, 2-(1,1-dimethylethyl)-(3602-55-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
RTECS DK3790000
HS Code 29146990
MSDS Information
ProviderLanguage
SigmaAldrich English
2-tert-Butyl-1,4-benzoquinone Usage And Synthesis
Chemical PropertiesYellow crystalline powder
Uses2-tert-Butyl-1,4-benzoquinone may be used in the synthesis of azatrioxa[8]circulene.
General Description2-tert-Butyl-1,4-benzoquinone (TBQ, TBBQ, tBQ, BuBQ, BQ , tert-butyl-p-quinone) is a 1,4-benzoquinone derivative. It is a major metabolite of the food additive, butylated hydroxyanisole (BHA). TBQ is reported to be strongly cytotoxic in human monocytic leukemia U937 cells. TBQ is an oxidation product of 2-tert-butylhydroquinone (TBHQ). Studies confirm that TBQ induces apoptosis and cell proliferation inhibition in chronic myelogenous leukemia (CML) cells. Its binding interactions with lysozyme has been examined and found to be intermediate between BHA and TBHQ. It has been reported to be synthesized by the titanium superoxide catalyzed oxidation of 2-tert-butylphenol using aq. 30% H2O2. TBQ is one of the main neoformed compounds from TBHQ decomposition in PLA-TBHQ film (Poly lactic acid).
2-tert-Butyl-1,4-benzoquinone Preparation Products And Raw materials
Preparation Products2-tert-butyl-1,4-dimethoxybenzene
2-tert-Butyl-1,4-benzoquinone 3,3'-di-tert-butylbiphenyldiquinone-(2,5,2',5') 4-tert-Butylcatechol Cyhalofop-butyl 4-tert-Butylphenol tert-Butyl methyl ether tert-Butyldimethylsilyl chloride tert-Butyl hydroperoxide Buprofezin Methyl 4-tert-butylbenzoate tert-Butanol Diethylene glycol monobutyl ether Butyl acrylate tert-Butylbenzene Butyl acetate 3,5-Di-tert-butyl-1,4-benzoquinone,2,6-DI-TERT-BUTYL-1,4-BENZOQUINONE 1,4-Benzoquinone 2-Butoxyethanol

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