ChemicalBook Product Catalog Chemical Reagents Organic reagents Phosphine ligand 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE

1,2-BIS(DIMETHYLPHOSPHINO)ETHANE

1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Basic information
Product Name:1,2-BIS(DIMETHYLPHOSPHINO)ETHANE
Synonyms:Bis(dimethylphosphino)ethane;1,2-Bis(dimethylphosphino)ethane,98%DMPE;1,2-BIS(DIMETHYLPHOSPHINO)ETHANE 97%;1,2-Bis(dimethylphosphino)ethane, (DMPE);DMPE, Ethylenebis(dimethylphosphine);1,2-Di(dimethylphosphino)ethane;1,2-Ethanediylbis[dimethylphosphine];Ethylenebis(dimethylphosphine)
CAS:23936-60-9
MF:C6H16P2
MW:150.14
EINECS:
Product Categories:Achiral Phosphine;Alkyl Phosphine;organophosphine ligand;Phosphine Ligands;Radiopharmaceutical Chemistry (Chelating Reagents);Synthetic Organic Chemistry;Ligand;Analytical Chemistry;Ligands for Pharmaceutical Research
Mol File:23936-60-9.mol
1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Structure
1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Chemical Properties
Melting point 0℃
Boiling point 180 °C(lit.)
density 0.9 g/mL at 25 °C(lit.)
refractive index n20/D 1.507(lit.)
Fp -16 °C
storage temp. Flammables area
form liquid
Specific Gravity0.90.900
color colorless
Sensitive Air & Moisture Sensitive
BRN 1732994
CAS DataBase Reference23936-60-9(CAS DataBase Reference)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-36/37/38
Safety Statements 16-26-36-36/37/39
RIDADR UN 1993 3/PG 2
WGK Germany 3
F 10-13-23
TSCA No
HazardClass 3
PackingGroup II
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Usage And Synthesis
Chemical PropertiesColorless to light yellow liqui
Uses1,2-Bis(dimethylphosphino)ethane (dmpe) may be employed as ligand in the preparation of cis-arylmethyl(dmpe) nickel(II) complexes.
General Description1,2-Bis(dimethylphosphino)ethane (dmpe) is a polydentate phosphine ligand. Synthesis of 1,2-bis(dimethylphosphino)ethane has been reported. It reacts with ZrCl2 to afford ZrCl4(dmpe)2 complexes.
1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Preparation Products And Raw materials
DICHLORO[1,2-BIS(DIMETHYLPHOSPHINO)ETHANE]PALLADATE (II) 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Dichloro[1,2-bis(dimethylphosphino)ethane]palladate (Ⅱ) Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE Dichloro[1,2-bis(dimethylphosphino)ethane]palladate () (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE tris(1,2-bis(dimethylphosphino)ethane)rhenium(I) 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride technetium Tc 99m tris(1,2-bis(dimethylphosphino)ethane) 1,2-ETHYLENE BIS(DIPHENYLPHOSPHINE OXIDE) 1,2-Bis(diphenylphosphino)ethane [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]TETRACARBONYLTUNGSTEN [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLOROPALLADIUM(II) (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE (-)-TETRAPHOS ([2S,3S]-BIS[DIPHENYLPHOSPHINO]BUTANE)(ETA3-ALLYL) PALLADIUM(II) PERCHLORATE R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE
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