3-PENTENENITRILE

3-PENTENENITRILE Basic information
Product Name:3-PENTENENITRILE
Synonyms:3-penetenenitrlle;3-pentenenitrile,[liquid];TRANS-3-PENTENENITRILE;3-PENTENENITRILE;3-PENTENONITRILE;crotyl cyanide;pent-3-enenitrile;3-PENTENENITRILE 90+%
CAS:4635-87-4
MF:C5H7N
MW:81.12
EINECS:225-060-7
Product Categories:C1 to C5;Cyanides/Nitriles;Nitrogen Compounds
Mol File:4635-87-4.mol
3-PENTENENITRILE Structure
3-PENTENENITRILE Chemical Properties
Boiling point 144-147 °C(lit.)
density 0.842 g/mL at 20 °C(lit.)
vapor pressure 24.9 mm Hg ( 50 °C)
refractive index n20/D 1.422
Fp 104 °F
CAS DataBase Reference4635-87-4
EPA Substance Registry System3-Pentenenitrile (4635-87-4)
Safety Information
Hazard Codes T
Risk Statements 10-23/24/25-36/37/38
Safety Statements 45-41-36/37/39-14
RIDADR UN 3275 6.1/PG 2
WGK Germany 3
HazardClass 3/6.1
PackingGroup II
Hazardous Substances Data4635-87-4(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
3-PENTENENITRILE Usage And Synthesis
General DescriptionA clear colorless to amber liquid. Less dense than water. Flash point 104°F. Boiling point 296°F. Generally stable and not liable to polymerization. May be toxic by skin absorption, inhalation or ingestion. Prolonged exposure may result in delayed cyanide poisoning. Avoid direct contact with vapors, mists or liquid. May produce cyanide gas and carbon monoxide during combustion. Used in the manufacture of various organic chemicals.
Air & Water ReactionsHighly flammable.
Reactivity ProfileNitriles, such as 3-PENTENENITRILE, may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids.
Health HazardInhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire Hazard3-PENTENENITRILE is combustible.
3-PENTENENITRILE Preparation Products And Raw materials
Preparation Products2-PENTENENITRILE
(E)-5-(3,4-Dichlorophenyl)-3-hydroxy-3-trifluoromethyl-4-pentenonitrile 3-Pentenenitrile,5-(1-aziridinyl)-(9CI) 2-PENTENENITRILE (E)-3-Methyl-5-phenyl-2-pentenenitrile 4-tert-butoxycarbonylamino-3-hydroxy-2-(2,3,4,5,6-pentafluorophenyl)-5-phenyl-2-pentenenitrile (R)-3-Hydroxy-5-phenyl-4-pentenenitrile (E)-2-Cyano-2-[1-(trifluoromethyl)-2,2,2-trifluoroethyl]-5-(methylthio)-4-pentenenitrile [R,(-)]-2-Hydroxy-3-pentenenitrile CIS-2-PENTENONITRILE,2-PENTENENITRILE (E)-5-Hydroxy-2-pentenenitrile 2-(p-Chlorophenyl)-3-isobutoxy-2-pentenenitrile 2-Phenyl-4-pentenenitrile (Z)-2-Cyano-2-[1-(trifluoromethyl)-2,2,2-trifluoroethyl]-5-methoxy-4-pentenenitrile (Z)-2-Cyano-2-[1-(trifluoromethyl)-2,2,2-trifluoroethyl]-5-ethoxy-4-pentenenitrile (E)-2-PENTENENITRILE 2-[(Methylthio)formyl]-4-pentenenitrile 2,3,5-Triphenyl-2,4-bis(1-piperidinyl)-4-pentenonitrile (Z)-3-methyl-5-phenyl-2-Pentenenitrile

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