Chlorodimethylphenylsilane

Chlorodimethylphenylsilane Basic information

Product Name:	Chlorodimethylphenylsilane
Synonyms:	CHLORODIMETHYLPHENYLSILANE;DMPSCI;DIMETHYLPHENYL-CHLOROSILANE;chlorodimethylphenyl-silan;CP0160;Dimethylphenylchlorosilane~Dimethylphenylsilyl chloride~DMPSCl~Phenyldimethylchlorosilane;Phenyldimethylchlorosilane(Chlorodimethylphenylsilane);Chlorodimethylphenylsilane,97%
CAS:	768-33-2
MF:	C8H11ClSi
MW:	170.71
EINECS:	212-193-0
Product Categories:	Monochlorosilanes;Si (Classes of Silicon Compounds);Si-Cl Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry
Mol File:	768-33-2.mol

Chlorodimethylphenylsilane Chemical Properties

Melting point	<0°C
Boiling point	194-198 °C
density	1.017 g/mL at 25 °C(lit.)
refractive index	n20/D 1.509(lit.)
Fp	143 °F
storage temp.	Inert atmosphere,Room Temperature
solubility	Miscible with tetrahydrofuran, ether and hexane.
form	clear liquid
Specific Gravity	1.017
color	Colorless to Light yellow
Water Solubility	MAY DECOMPOSE
Hydrolytic Sensitivity	8: reacts rapidly with moisture, water, protic solvents
Sensitive	Moisture Sensitive
BRN	606292
InChIKey	KWYZNESIGBQHJK-UHFFFAOYSA-N
CAS DataBase Reference	768-33-2(CAS DataBase Reference)
NIST Chemistry Reference	Silane, chlorodimethylphenyl-(768-33-2)
EPA Substance Registry System	Silane, chlorodimethylphenyl- (768-33-2)

Safety Information

Hazard Codes	C
Risk Statements	34-37
Safety Statements	26-36/37/39-45
RIDADR	UN 2987 8/PG 2
WGK Germany	1
F	10-21
TSCA	Yes
HazardClass	8
PackingGroup	II
HS Code	29319090

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

Chlorodimethylphenylsilane Usage And Synthesis

Chemical Properties	clear colorless to light yellow liquid
Uses	Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.
Purification Methods	Fractionate it through a 1.5 x 18inch column packed with stainless steel helices, or a spinning band column. [Daudt & Hyde J Am Chem Soc 74 386 1952, Lewis et al. J Am Chem Soc 70 1115 1948, Eaborn J Chem Soc 494 1953.] It is used for standardising MeLi or MeMgBr which form Me3PhSi which is estimated by GC. [Maienthal et al. J Am Chem Soc 76 6392 1954, House & Respess J Organomet Chem 4 95 1965, Beilstein 16 IV 1475.] TOXIC and MOISTURE SENSITIVE.

Chlorodimethylphenylsilane Preparation Products And Raw materials

Raw materials	Diethyl ether-->Tetrahydrofuran-->PETROLEUM ETHER-->Toluene-->Hexane-->Nitrogen-->Magnesium-->Triphenylphosphine-->Iodine-->Bromobenzene-->Benzoyl chloride-->Copper(I) Cyanide-->Lithium-->Dichlorodimethylsilane-->Bis(benzonitrile)palladium chloride-->CHLORO(DIETHYLAMINO)DIMETHYLSILANE 97
Preparation Products	(DIMETHYLPHENYLSILYL)BORONIC ACID PINAC&

CHLOROMETHYLPHENYLSILANE P-TOLYLDIMETHYLCHLOROSILANE 1,4 BIS(DIMETHYLCHLOROSILYL)BENZENE PHENYLMETHYLVINYLCHLOROSILANE PHENYLHEXYLMETHYL CHLOROSILANE BIPHENYLDIISOPROPYLSILYL CHLORIDE DIMETHYLTHEXYLSILYL CHLORIDE METHYLPHENYLSILANE DIPHENYLVINYLCHLOROSILANE CHLOROMETHYL-METHYL-PHENYL-CHLOROSILANE BIPHENYLDIMETHYLSILYL CHLORIDE DIMETHYLSILANE 1-(4-METHOXYPHENYL)-1-CHLOROSILACYCLOBUTANE 9-(CHLORODIPHENYLSILYL)-9H-FLUORENE M-PHENOXYPHENYLDIMETHYLCHLOROSILANE CHLOROPHENYLSILANE 97 Chlorodimethylpentafluorophenylsilane 3,5-BIS(TRIFLUOROMETHYL)PHENYLDIMETHYLCHLOROSILANE

Email:[email protected] [email protected]

Copyright © 2024 Mywellwork.com All rights reserved.