ChemicalBook Product Catalog Organic Chemistry Alcohols,Phenols,Phenol alcohols cyclitols 2-Aminobenzyl alcohol

2-Aminobenzyl alcohol

2-Aminobenzyl alcohol Basic information
Product Name:2-Aminobenzyl alcohol
Synonyms:o-amino-benzylalcoho;o-Aminobenzylic alcohol;o-aminobenzylicalcohol;2-AMINOBENZYL ALCOHOL 98%;O-ACETAMINOPHENOL;2-Aminobenzene-1-methanol;o-Aminobenzenemethanol;2-Aminobenzyl alcohol,98%
CAS:5344-90-1
MF:C7H9NO
MW:123.15
EINECS:226-293-7
Product Categories:Benzhydrols, Benzyl & Special Alcohols
Mol File:5344-90-1.mol
2-Aminobenzyl alcohol Structure
2-Aminobenzyl alcohol Chemical Properties
Melting point 81-83 °C(lit.)
Boiling point 162 °C15 mm Hg(lit.)
density 1.0877 (rough estimate)
refractive index 1.4905
Fp 160°C/10mm
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka14.21±0.10(Predicted)
form Crystalline Powder
color Beige to gray-brown
Water Solubility Very soluble in water.
BRN 1072211
InChIKeyVYFOAVADNIHPTR-UHFFFAOYSA-N
CAS DataBase Reference5344-90-1(CAS DataBase Reference)
NIST Chemistry Reference2-Aminobenzyl alcohol(5344-90-1)
EPA Substance Registry System2-Aminobenzenemethanol (5344-90-1)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36-37/39
WGK Germany 3
RTECS DN3155000
F 8-10-23
Hazard Note Irritant
TSCA Yes
HS Code 29221980
MSDS Information
ProviderLanguage
2-Hydroxymethyl aniline English
SigmaAldrich English
ACROS English
ALFA English
2-Aminobenzyl alcohol Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powder.
Uses2-Aminobenzyl alcohol was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.
ApplicationA double dehydrogenative coupling of 2-aminobenzyl alcohol with secondary aryl alcohols furnishes 2-arylquinolines in good to excellent yields under mild and sustainable conditions. The reaction is catalyzed by the molecularly defined phosphine-free nickel complex.
General Description2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde.
storage Keep Cold. Air Sensitive. Light Sensitive.
2-Aminobenzyl alcohol Preparation Products And Raw materials
Preparation ProductsMianserin hydrochloride-->2-(2-AMINOPHENYL)BENZOTHIAZOLE 97-->Dimethyl 2,3-quinolinedicarboxylate-->2-AMINOSTYRENE-->3-Methoxyquinoline-->2-(Hydroxymethyl)benzonitrile-->2-Iodobenzyl bromide-->2-(2-PYRIDYL)BENZIMIDAZOLE-->Quinoline, 2-(3-bromophenyl)--->2-(2-chlorophenyl)quinazoline-->Quinoline, 2-cyclopropyl-
R-(-)-Mianserin DESMETHYL MIANSERIN Mianserin-d3 Dihydrochloride [2-(4-methyl-2-phenylpiperazin-1-yl)phenyl]methanol 2-AMINO-3,5-DIBROMOBENZYL ALCOHOL 4-Aminobenzyl alcohol 2-Aminobenzyl alcohol 2-Aminobenzonitrile 2-Nitrobenzyl alcohol ALTRENOGEST N-Acetylanthranilic acid Acid Blue 93 Hydroxymethyl o-Aminophenylacetic acid Flufenamic acid 2-Aminobenzaldehyde (2-AMINO-PYRIDIN-4-YL)-METHANOL AMINO ACIDS
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