2-Chlorobenzyl alcohol

2-Chlorobenzyl alcohol Basic information

Product Name:	2-Chlorobenzyl alcohol
Synonyms:	Benzenemethanol,2-chloro-;Benzyl alcohol, o-chloro-;o-chlorobenzoylalcohol;ortho-Chlorobenzyl alcohol;o-Chlorobenzyl Alcohol 2-Chlorobenzyl Alcohol;2-Chlorobenzyl alcohol 98%;2-Chlorobenzenemehtanol;2-Chlorobenzyl alcohol,99%
CAS:	17849-38-6
MF:	C7H7ClO
MW:	142.58
EINECS:	241-801-7
Product Categories:	Building Blocks;C6 to C8;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds;Aromatics;Benzhydrols, Benzyl & Special Alcohols;Alcohol;Alcohols;Chlorine Compounds;Organic Building Blocks;Oxygen Compounds;Phenols
Mol File:	17849-38-6.mol

2-Chlorobenzyl alcohol Chemical Properties

Melting point	69-71 °C (lit.)
Boiling point	227 °C (lit.)
density	1.1104 (rough estimate)
refractive index	1.5390 (estimate)
Fp	227°C
storage temp.	Sealed in dry,Room Temperature
solubility	chloroform: soluble25mg/mL, clear, colorless
pka	13.99±0.10(Predicted)
form	Fine Crystalline Powder
color	White
BRN	2042182
LogP	1.770
CAS DataBase Reference	17849-38-6(CAS DataBase Reference)
NIST Chemistry Reference	Benzenemethanol, 2-chloro-(17849-38-6)
EPA Substance Registry System	2-Chlorobenzenemethanol (17849-38-6)

Safety Information

Hazard Codes	Xi
Safety Statements	22-24/25
WGK Germany	3
Hazard Note	Irritant
HS Code	29062900

MSDS Information

Provider	Language
o-Chlorobenzyl alcohol	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Chlorobenzyl alcohol Usage And Synthesis

Chemical Properties	white fine crystalline powder
Uses	(2-Chlorophenyl)methanol is used as a reactant in the preparation of aldehydes and ketones using transition metal free aerobic oxidation and catalyzed by TEMPO/Br2/NaNO2.
Synthesis Reference(s)	Journal of the American Chemical Society, 69, p. 2548, 1947 DOI: 10.1021/ja01202a082 Synthetic Communications, 25, p. 1689, 1995 DOI: 10.1080/00397919508015853
General Description	Major urinary metabolites of 2-chlorobenzyl alcohol in rats were 2-chlorohippuric acid, 2-chlorobenzyl cysteine, 2-chlorobenzoic acid and 2-chlorobenzyl glucuronic acid. It is a possible intermediate formed during the metabolism of 2-chloromandelic acid.

2-Chlorobenzyl alcohol Preparation Products And Raw materials

Raw materials	2-CHLORO-5-HYDROXYBENZOIC ACID-->BenzeneMethanaMine, 2-chloro-N,N-diMethyl--->Benzaldehyde-->Dimethylamine-->2-Chlorobenzoyl chloride-->2-Chlorotoluene-->2-Chlorobenzaldehyde
Preparation Products	N-Boc-N'-(2-chlorobenzyloxycarbonyl)-L-lysine-->H-LYS(2-CL-Z)-OH-->2-(2-chlorophenyl)-4,6-diphenyl-1,3,5-triazine-->2-CHLOROBENZYL CHLOROFORMATE-->[(2-Chlorophenyl)methylene]malononitrile-->5-(2-CHLOROPHENYL)-1H-TETRAZOLE-->2-Chlorostyrene-->2-CHLOROBENZOYLACETONITRILE

(R)-α-Methyl-4-chlorobenzyl alcohol 2-AMINO-5-CHLOROBENZYL ALCOHOL 4-BENZYLOXY-2-CHLOROBENZYL ALCOHOL 3-CHLOROBENZYL ALCOHOL [METHYLENE-14C] 3-Chlorobenzyl alcohol 98%,M-CHLOROBENZYL ALCOHOL,3-CHLOROBENZYL ALCOHOL 2-AMINO-5-CHLOROBENZYL ALCOHOL (+)-a-Aminomethyl-o-chlorobenzyl alcohol Chlorophenyl (S)-α-Methyl-3-chlorobenzyl alcohol alpha-[(tert-butylamino)methyl]-o-chlorobenzyl alcohol hydrochloride α-[2,2-Bis(methylthio)vinyl]-4-chlorobenzyl alcohol α-Methyl-4-chlorobenzyl alcohol α-Cyclopropyl-α-methyl-4-chlorobenzyl alcohol α-(2-Pyridyl)-α-(4-chlorophenyl)-4-chlorobenzyl alcohol chlorobenzyl alcohol 2-BROMO-5-CHLOROBENZYL ALCOHOL 2-(Chloromethyl)benzonitrile α-[(Benzylethylamino)methyl]-4-chlorobenzyl alcohol

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