ETHYLENE SULFIDE

ETHYLENE SULFIDE Basic information
Product Name:ETHYLENE SULFIDE
Synonyms:2,3-Dihydrothiirene;aethylensulfid;Ethylene episulfide;Ethylene episulphide;Ethylene sulphide;ethyleneepisulfide;ethyleneepisulphide;ethylenesulphide
CAS:420-12-2
MF:C2H4S
MW:60.12
EINECS:206-993-9
Product Categories:Building Blocks;Chemical Synthesis;Simple 3-Membered Ring Compounds;Organic Building Blocks;Sulfides/Disulfides;Sulfur Compounds;Thiiranes
Mol File:420-12-2.mol
ETHYLENE SULFIDE Structure
ETHYLENE SULFIDE Chemical Properties
Melting point 207-209℃
Boiling point 55-56 °C (lit.)
density 1.01 g/mL at 25 °C (lit.)
vapor pressure 4.15 psi ( 20 °C)
refractive index n20/D 1.495(lit.)
Fp 50 °F
storage temp. -20°C
Water Solubility Insoluble in water
solubility Chloroform (Soluble), Methanol (Sparingly)
form liquid
color Colorless to Almost colorless
BRN 102379
Stability:Stable at room temperature, but may have butylmercaptan added to enhance stability. Flammable.
LogP0.556 (est)
CAS DataBase Reference420-12-2(CAS DataBase Reference)
IARC3 (Vol. 11, Sup 7) 1987
EPA Substance Registry SystemThiirane (420-12-2)
Safety Information
Hazard Codes F,T
Risk Statements 11-23/25-41-43
Safety Statements 16-36/37/39-45-39-26
RIDADR UN 1992 3/PG 2
WGK Germany 3
RTECS KX3500000
10-13-23
HazardClass 6.1(a)
PackingGroup I
HS Code 29349990
Hazardous Substances Data420-12-2(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ETHYLENE SULFIDE Usage And Synthesis
Chemical Propertiesclear colourless liquid
Uses
  • Ethylene sulfide is generally used in the preparation of organosulfur compounds, especially for mercaptoethylation of primary and secondary amines to obtain aminothiols.
  • It is used in the synthesis of dendritic thioether ligands to stabilize gold nanoparticles (Au NPs).
  • Chitosan can be chemically modified by treating ethylene sulfide to obtain a biopolymer for the removal of divalent cations from aqueous solutions.

DefinitionChEBI: Thiirane is a saturated organic heteromonocyclic parent and an organosulfur heterocyclic compound.
Safety ProfilePoison by ingestion, intraperitoneal, and subcutaneous routes. Mddly toxic by inhalation. A skin, eye, and mucous membrane irritant. Questionable carcinogen with experimental tumorigenic data. Can react with oxidizing materials. When heated to decomposition, or on contact with acid or acid fumes, it emits highly toxic fumes of SOx. See also SULFIDES.
2-ETHYLTHIIRANE ETHYLENE SULFIDE (CHLOROMETHYL)ETHYLENE SULFIDE p-Chlorothiobenzoic acid S-2,3-epithiopropyl ester PROPYLENE SULFIDE ISOBUTYLENE SULFIDE 3,6-DITHIA-BICYCLO[3.1.0]HEXANE 3,3-DIOXIDE 1,3-Dihydro-1-(oxiranylmethyl)-3-(thiiranylmethyl)-2H-benzimidazol-2-o ne 1-cyano-3,4-epithiobutane AKOS BC-0967 Mepitiostane 3-(4-PHENOXYPHENYLSULFONYL)PROPYLTHIIRANE (S)-(-)-1,2-EPITHIODECANE (S)-(-)-1,2-EPITHIODODECANE MMP-2/MMP-9 INHIBITOR IV (S)-(-)-1,2-EPITHIOOCTANE AKOS BB-8996 Epitiostanol

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