ChemicalBook Product Catalog Inorganic chemistry Inorganic salts Metal halide and Halogen salt Metal chlorides and salt MOLYBDENUM (III) CHLORIDE

MOLYBDENUM (III) CHLORIDE

MOLYBDENUM (III) CHLORIDE Basic information
Product Name:MOLYBDENUM (III) CHLORIDE
Synonyms:molybdenumchloride(mocl3);Molybdenum(III)chloride,99.5%(metalsbasis);Molybdenum(III)chloride(99.5%-Mo);trichloromolybdenum;MOLYBDENUM(III) CHLORIDE: 99.5%;Einecs 236-775-9;MOLYBDENUM (III) CHLORIDE, 99%MOLYBDENUM (III) CHLORIDE, 99%MOLYBDENUM (III) CHLORIDE, 99%;MOLYBDENUM CHLORIDE (III), 99%
CAS:13478-18-7
MF:Cl3Mo
MW:202.3
EINECS:236-775-9
Product Categories:metal halide;Molybdenum Salts;MolybdenumMetal and Ceramic Science;Catalysis and Inorganic Chemistry;Chemical Synthesis;Salts
Mol File:13478-18-7.mol
MOLYBDENUM (III) CHLORIDE Structure
MOLYBDENUM (III) CHLORIDE Chemical Properties
Melting point 1027°C
density 3.58 g/mL at 25 °C(lit.)
solubility H2O: insoluble(lit.)
form Powder
color Dark red
Specific Gravity3.59
Water Solubility Soluble in nitric acid and sulfuric acid. Insoluble in water and dilute hydrochloric acid. Slightly soluble in ethanol and diethyl ether.
Sensitive Air & Moisture Sensitive
Exposure limitsACGIH: TWA 0.5 mg/m3; TWA 10 mg/m3; TWA 3 mg/m3
NIOSH: IDLH 1000 mg/m3; IDLH 5000 mg/m3
CAS DataBase Reference13478-18-7
EPA Substance Registry SystemMolybdenum chloride (MoCl3) (13478-18-7)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
RIDADR UN3260
WGK Germany 3
RTECS QA4681400
TSCA Yes
HazardClass 8
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
MOLYBDENUM (III) CHLORIDE Usage And Synthesis
Chemical Properties-100 mesh with 99.5% purity; purple crystal(s) [STR93] [CER91]
UsesMolybdenum(III) chloride reacts with tetrahydrothiophene to form complexes, which catalyze the polymerization and cyclotrimerization of alkynes.
DefinitionChEBI: Molybdenum trichloride is a molybdenum halide.
Purification MethodsBoil it with 12M HCl, wash it with absolute EtOH and dry it in a vacuum desiccator. It is a brown-red powder soluble in H2O, EtOH or Et2O and gives a blue solution in conc H2SO4. [Hein & Herzog Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1404 1965.]
MOLYBDENUM (III) CHLORIDE Preparation Products And Raw materials
Preparation ProductsMolybdenum
Cobalt(II) hydroxide Cerium Nitrate Cobalt hydroxide Potassium Phosphate Monobasic EUROPIUM(III) SULFATE HYDRATE Magnesium chloride hexahydrate MOLYBDENUM TETRACHLORIDE DIMETHOXYETHANE COMPLEX MOLYBDENUM (VI) TETRACHLORIDE OXIDE MOLYBDENUM (III) CHLORIDE Molybdenum chloride (MoCl5),MOLYBDENUM CHLORIDE CYCLOPENTADIENYLMOLYBDENUM (V) TETRACHLORIDE BIS(ACETONITRILE)MOLYBDENUM(IV) CHLORIDE molybdenum tetrachloride MOLYBDENUM CHLORIDE Molybdenum chloride oxide MOLYBDENUM (V) TRICHLORIDE-ISOPROPOXIDE POTASSIUM HEXACHLOROMOLYBDATE Molybdenum
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