Diphenyliodonium hexafluorophosphate

Diphenyliodonium hexafluorophosphate Basic information
Product Name:Diphenyliodonium hexafluorophosphate
Synonyms:iodonium diphenyl hexafluorophosphate;DIHP;DIPHENYLIODINIUM HEXAFLUOROPHOSPHATE;DIPHENYLIODONIUM HEXAFLUOROPHOSPHATE;DIHFP;diphenyliodoniuM hexafluorophosphate(V);DPIHFP;Iodonium,diphenyl-,hexafluorophosphate(1-)(1:1)
CAS:58109-40-3
MF:C12H10F6IP
MW:426.08
EINECS:261-134-5
Product Categories:Diphenyliodonium Compounds;Functional Materials;Hypervalent Iodine Compounds;Iodonium Sulfonium & Oxonium Compounds;Photopolymerization Initiators;Synthetic Organic Chemistry;Cationic PhotoinitiatorsMicro/Nanoelectronics;FluoridesSelf Assembly&Contact Printing;Electronic Chemicals;Organic Photoinitiators;Photoacid Generators (PAGs);Hypervalent Iodine;Oxidation;Synthetic Reagents;Photoresists;Polymerization Initiators
Mol File:58109-40-3.mol
Diphenyliodonium hexafluorophosphate Structure
Diphenyliodonium hexafluorophosphate Chemical Properties
Melting point 140-144 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Soluble in tetrahydrofuran, ethyl acetate, methanol, acetonitrile, dimethylformamide, dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes, hexanes, toluene and diethyl ether.
form Crystalline
color White to Almost white
Sensitive Light Sensitive
BRN 4343861
CAS DataBase Reference58109-40-3(CAS DataBase Reference)
EPA Substance Registry SystemIodonium, diphenyl-, hexafluorophosphate(1-) (58109-40-3)
Safety Information
Hazard Codes C,Xi
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 1759 8/PG 3
WGK Germany 3
8-10-21
Hazard Note Irritant
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Diphenyliodonium hexafluorophosphate Usage And Synthesis
UsesDiphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.
Diphenyliodonium hexafluorophosphate Preparation Products And Raw materials
Sodium hexafluorophosphate O-DIPHENYLPHOSPHINYLHYDROXYLAMINE Diphenyl diselenide Hexafluorophosphate Diphenyliodonium hexafluorophosphate Biphenyl DIPHENYLIODONIUM IODIDE diphenyliodonium hexafluorophosphate(1-) I-oxide Diphenylmethane Bis(4-methylphenyl)iodonium hexafluorophosphate Hexafluorophosphoric acid Bis(4-tert-butylphenyl)iodonium hexafluorophosphate Chlorodiphenylphosphine Potassium hexafluorophosphate Lithium hexafluorophosphate tert-Butylchlorodiphenylsilane

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