TRIS(TRIMETHYLSILYL)METHANE

TRIS(TRIMETHYLSILYL)METHANE Basic information
Product Name:TRIS(TRIMETHYLSILYL)METHANE
Synonyms:TRIS(TRIMETHYLSILYL)METHANE 97+%;Tris(trimethylsilyl)methane,min.97%;Tris(trimethylsilyl)methane, min. 97%;2,2,4,4-Tetramethyl-3-(trimethylsilyl)-2,4-disilapentane;Methanetriyltris(trimethylsilane);Methylidynetris(trimethylsilane);Tris(trimethylsilyl)methane,93%;1,1',1''-Methylidynetris[1,1,1-trimethylsilane]
CAS:1068-69-5
MF:C10H28Si3
MW:232.59
EINECS:
Product Categories:organosilicon compounds;Organometallic Reagents;Organosilicon;Others
Mol File:1068-69-5.mol
TRIS(TRIMETHYLSILYL)METHANE Structure
TRIS(TRIMETHYLSILYL)METHANE Chemical Properties
Boiling point 55-56 °C/2 mmHg (lit.)
density 0.827 g/mL at 25 °C (lit.)
refractive index n20/D 1.464(lit.)
Fp 170 °F
solubility sol common organic solvents.
form liquid
color colorless
Specific Gravity0.827
Hydrolytic Sensitivity1: no significant reaction with aqueous systems
BRN 1850371
CAS DataBase Reference1068-69-5
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
TSCA No
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
TRIS(TRIMETHYLSILYL)METHANE Usage And Synthesis
Chemical PropertiesCLEAR COLORLESS LIQUID
Physical propertiesbp 219 °C, 93–95 °C/13.5 mmHg; d 0.836 g cm?3; n20 D 1.4657.
UsesTris(trimethylsilyl)methane is precursor of (Me3Si)3CLi, useful to introduce bulky tris(trimethylsilyl)methyl (trisyl) group; Peterson alkenation reagent. It takes part in the reactions of Synthesis of Tris(trimethylsilyl)methyl Bromide, Metalation, Formation of Bis(trimethylsilyl)methyllithium, Hydrosilylation of Double Bonds, Intramolecular Reactions, Intermolecular Reactions, Nonradical Reactions etc.
UsesSterically demanding "risyl"group.
TRIS(TRIMETHYLSILYL)METHANE Preparation Products And Raw materials
TRIS(TRIMETHYLSILYL)GERMANIUM HYDRIDE 3-(triethoxysilyl)-N,N-bis-3-(triethoxysilyl)-propyl-Propane-1-amine Propane-1-amine,3-(triethoxysilyl)-N,N-bis-3-(triethoxysilyl)-propyl- Tris(trimethylsilyloxy)ethylene TRIS(DIMETHYLAMINO)SILANE TRIS(TRIMETHYLSILOXY)SILANE Sulfamide TRIS(DIMETHYLSILYL)AMINE [TRIS(TRIMETHYLSILOXY)SILYLETHYL]DIMETHYLCHLOROSILANE Valine Chloromethyltrimethylsilane Benzonitrile TRIS(TRIMETHYLSILYL)METHANE SALOR-INT L170658-1EA Bis(trimethylsilyl)methane Tetramethylsilane AURORA KA-1820 1,3-DISILABUTANE 1,3-DISILAPROPANE

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