Tetraphenylethylene

Tetraphenylethylene Basic information
Product Name:Tetraphenylethylene
Synonyms:1,1’,1’’,1’’’-(1,2-ethenediylidene)tetrakis-benzen;Tetraphenylethlene;alpha,beta-Diphenylstilbene;ethene,tetraphenyl-;Ethylene, tetraphenyl-;Tetraphenyl$thylen;Tetraphenylethylene,~98%;Benzene, 1,1,1,1-(1,2-ethenediylidene)tetrakis-
CAS:632-51-9
MF:C26H20
MW:332.44
EINECS:211-179-1
Product Categories:Organic Building Blocks;Acyclic;Alkenes
Mol File:632-51-9.mol
Tetraphenylethylene Structure
Tetraphenylethylene Chemical Properties
Melting point 222-224 °C (lit.)
Boiling point 420 °C (lit.)
density 1.1550
refractive index 1.4800 (estimate)
Fp 420°C
storage temp. Sealed in dry,Room Temperature
solubility Soluble in hot toluene
form Solid
color White to Off-White
Water Solubility insoluble
BRN 1913548
InChIKeyJLZUZNKTTIRERF-UHFFFAOYSA-N
CAS DataBase Reference632-51-9(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1,1',1'',1'''-(1,2-ethenediylidene)tetrakis-(632-51-9)
EPA Substance Registry SystemBenzene, 1,1',1'',1'''-(1,2-ethenediylidene)tetrakis- (632-51-9)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
TSCA Yes
HS Code 2903780090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Tetraphenylethylene Usage And Synthesis
Chemical PropertiesWHITE TO LIGHT BEIGE CRYSTALLINE POWDER
Uses1,1,2,2-Tetraphenylethylene is used as a reagent in the synthesis of a dynamic covalent imine gel as a luminescent sensor. Studies show that 1,1,2,2-Tetraphenylethylene (TPE) can assemble into self-luminescent nanoparticles which are part of a drug delivery system that shows aggregation-induced emission and can be easily tracked in cells.
Purification MethodsCrystallise the ethylene from dioxane or from EtOH/*C6H6. Sublime it under high vacuum. [Beilstein 5 H 743, 5 IV 2780.]
Tetraphenylethylene Preparation Products And Raw materials
Preparation ProductsBENZIL DIHYDRAZONE-->1,1-diphenyl-2,2-di(p-bromophenyl)ethylene
Tetraphenyltin EPDM RUBBER Tetrapropylammonium hydroxide Polyethylene Butyl acrylate POLYPHENYL ETHER (5 RINGS) OS-124, STAT. PHASE FOR GC acrylonitrile-butadiene rubber Phthalates TRANS-1,3-DIPHENYL-2-PROPEN-1-OL Titanium tetrachloride SILICONE RUBBER Polyvinyl chloride TETRAPHENYLETHYLENE DIPHOSPHITE 5G [R] TETRAPHENYLETHYLENE DIPHOSPHITE TETRAPHENYLETHYLENE GLYCOL TETRAPHENYLETHYLENE TETRAPHENYLETHYLENE OXIDE

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