DI-MICRO-CHLOROBIS[2-[(DIMETHYLAMINO)METHYL]PHENYL-C,N]DIPALLADIUM

DI-MICRO-CHLOROBIS[2-[(DIMETHYLAMINO)METHYL]PHENYL-C,N]DIPALLADIUM Basic information
Reaction
Product Name:DI-MICRO-CHLOROBIS[2-[(DIMETHYLAMINO)METHYL]PHENYL-C,N]DIPALLADIUM
Synonyms:DI-MICRO-CHLOROBIS[2-[(DIMETHYLAMINO)METHYL]PHENYL-C,N]DIPALLADIUM;di-mu-chlorobis(2-((dimethylamino)methyl)-phenyl-;Di-mu-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium;di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-c,n]dipalladium(ii);DI-MU-CHLOROBIS(2-((DIMETHYLAMINO)-METHYL)PHENYL-C,N)- DIPALLDIUM);dichlorobis(2-(dimethylamino)methyl)phenyl)dipalladium;Di-mu-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II);Di-μ-chlorobis[2-[(diMethylaMino)Methyl]phenyl-C,N]dipalladiuM(II),98%
CAS:18987-59-2
MF:C18H24Cl2N2Pd2+2
MW:552.14
EINECS:
Product Categories:Pd;Catalysis and Inorganic Chemistry;Homogeneous Pd Catalysts;Palladium
Mol File:18987-59-2.mol
DI-MICRO-CHLOROBIS[2-[(DIMETHYLAMINO)METHYL]PHENYL-C,N]DIPALLADIUM Structure
DI-MICRO-CHLOROBIS[2-[(DIMETHYLAMINO)METHYL]PHENYL-C,N]DIPALLADIUM Chemical Properties
Melting point 175 °C (dec.)(lit.)
form Powder
color yellow
InChIKeyLXPDULNZJMDUTK-UHFFFAOYSA-L
CAS DataBase Reference18987-59-2
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 2931.90.6000
MSDS Information
ProviderLanguage
SigmaAldrich English
DI-MICRO-CHLOROBIS[2-[(DIMETHYLAMINO)METHYL]PHENYL-C,N]DIPALLADIUM Usage And Synthesis
ReactionUseful starting material for the preparation of N-heterocyclic-carbene palladium complexes.
UsesCatalyst for:
  • Oxidative allylic C-H silylation
  • Transesterification reactions
  • Suzuki-Miyaura cross-coupling reactions
  • Stereocontrolled homologation of carbon chain boronic esters using Hoppe′s lithiated carbamates
  • Oxidative carbonylation reactions
  • Buchwald-Hartwig reactions
  • Mizoroki-Heck reaction
DI-MICRO-CHLOROBIS[2-[(DIMETHYLAMINO)METHYL]PHENYL-C,N]DIPALLADIUM Preparation Products And Raw materials
Raw materialsN,N-Dimethylbenzylamine-->Sodium chloride
1-(2,6-Dichlorophenyl)-2-indolinone Dicloxacillin DI-MICRO-CHLOROBIS[2-[(DIMETHYLAMINO)METHYL]PHENYL-C,N]DIPALLADIUM

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