ChemicalBook Product Catalog Chemical Reagents Silane reagent Benzylchlorodimethylsilane

Benzylchlorodimethylsilane

Benzylchlorodimethylsilane Basic information
Product Name:Benzylchlorodimethylsilane
Synonyms:BENZYLCHLORODIMETHYLSILANE;BENZYLDIMETHYLCHLOROSILANE;Dimethylchlorobenzylsilane;Benzyldimethylchlorisilane;Benzene, [(chlorodiMethylsilyl)Methyl]-;benzylchlorodimethyl-silan;chlorodimethyl(phenylmethyl)-silan;Benzylchlorodimethylsilane>
CAS:1833-31-4
MF:C9H13ClSi
MW:184.74
EINECS:
Product Categories:Monochlorosilanes;Protection & Derivatization Reagents (for Synthesis);Si (Classes of Silicon Compounds);Si-Cl Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Protecting and Derivatizing Reagents;Protection and Derivatization;Silicon-Based
Mol File:1833-31-4.mol
Benzylchlorodimethylsilane Structure
Benzylchlorodimethylsilane Chemical Properties
Melting point <0°C
Boiling point 101-103 °C/18 mmHg (lit.)
density 1.018 g/mL at 25 °C (lit.)
refractive index n20/D 1.511(lit.)
Fp 194 °F
form clear liquid
color Colorless to Almost colorless
Specific Gravity1.016
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
InChIKeyABHNFDUSOVXXOA-UHFFFAOYSA-N
CAS DataBase Reference1833-31-4(CAS DataBase Reference)
EPA Substance Registry SystemSilane, chlorodimethyl(phenylmethyl)- (1833-31-4)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 2987 8/PG 2
WGK Germany 3
RTECS VV1810000
TSCA Yes
HS Code 2931.90.6000
HazardClass 8
PackingGroup II
ToxicityLD50 ivn-mus: 56 mg/kg CSLNX* NX#04165
MSDS Information
ProviderLanguage
SigmaAldrich English
Benzylchlorodimethylsilane Usage And Synthesis
UsesBenzylchlorodimethylsilane can be used to prepare:
  • A ferrocene based mesoporous catalyst, applicable in the oxidation of styrene.
  • Silylbissulfide named 3-(benzyldimethylsilyl)-1,3-bis(phenylthio)-1-propene.
  • Silyl enyne by reacting with 6-hept-1-yne and nBu-Li, for further use in the intramolecular cross-metathesis to yield silicon substituted diene.

Safety ProfilePoison by intravenous route.When heated to decomposition it emits toxic vapors ofCl- .
Benzylchlorodimethylsilane Preparation Products And Raw materials
Preparation Products[2-(Benzyldimethylsilyl)phenyl]methanol
Benzylchlorodimethylsilane 3-CYANOPROPYLMETHYLDICHLOROSILANE ALPHA-(CHLORODIMETHYLSILYL)CUMENE CHLOROTRIBENZYLSILANE DIMETHYLTHEXYLSILYL CHLORIDE Benzyl chloride Dimethyldimethoxysilane Chlorodimethylsilane tert-Butyldimethylsilyl chloride Benzyldimethylcarbinyl butyrate 3,6-BIS[(1,1-DIMETHYLETHYL)-9H-FLUOREN-9-YL]CHLORODIMETHYL-SILANE 9-(CHLORODIPHENYLSILYL)-9H-FLUORENE Diethoxydimethylsilane 9-(CHLORODIMETHYLSILYL)-9H-FLUORENE Dichlorodimethylsilane 3-Chloropropyltrimethoxysilane Chloromethyl silane
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