Methyl tiglate

Methyl tiglate Basic information
Product Name:Methyl tiglate
Synonyms:TIGLIC ACID METHYL ESTER;METHYL E-2,3-DIMETHYLACRYLATE;METHYL-TRANS-2-METHYL-2-BUTENOATE;METHYL TIGLATE;(E)-2-Methyl-but-2-enoicacidmethylester;2-Butenoic acid, 2-methyl-, methyl ester, (E)-;2-Butenoicacid,2-methyl-,methylester,(2E)-;2-Carbomethoxy-2-butene, (E)-
CAS:6622-76-0
MF:C6H10O2
MW:114.14
EINECS:229-575-8
Product Categories:Aromatic Esters
Mol File:6622-76-0.mol
Methyl tiglate Structure
Methyl tiglate Chemical Properties
Melting point 37.22°C (estimate)
Boiling point 137-138 °C758 mm Hg(lit.)
density 0.95 g/mL at 25 °C(lit.)
refractive index n20/D 1.436(lit.)
Fp 95 °F
storage temp. Flammables area
form clear liquid
color Colorless to Almost colorless
Odorat 10.00 % in dipropylene glycol. ethereal rum
Odor Typeethereal
Water Solubility Soluble in alcohol, water 3813 mg/L @ 25°C (est).
Merck 14,9433
BRN 1720455
Stability:Stable. Flammable. Incompatible with strong oxidising agents.
LogP1.869 (est)
CAS DataBase Reference6622-76-0(CAS DataBase Reference)
NIST Chemistry ReferenceMethyl tiglate(6622-76-0)
EPA Substance Registry System2-Butenoic acid, 2-methyl-, methyl ester, (2E)- (6622-76-0)
Safety Information
Risk Statements 10
Safety Statements 16
RIDADR UN 3272 3/PG 3
WGK Germany 2
RTECS EM9254600
TSCA Yes
HS Code 2915.60.5000
HazardClass 3
PackingGroup III
MSDS Information
ProviderLanguage
Methyl 2-methylcrotonate English
SigmaAldrich English
ACROS English
ALFA English
Methyl tiglate Usage And Synthesis
Chemical Propertiescolourless liquid
UsesMethyl Tiglate is a useful reactant in elaboration of conjugagted alkenes initiated by insertion into a vinylic C-H bond.
DefinitionChEBI: Methyl tiglate is a fatty acid ester.
Synthesis Reference(s)Journal of the American Chemical Society, 108, p. 3016, 1986 DOI: 10.1021/ja00271a034
Methyl tiglate Preparation Products And Raw materials
Methyl tiglate Maleic acid Methyl cellulose METHYL JASMONATE Tiglic acid Methyl cinnamate METHYL 3-BUTENOATE Fumaric acid METHYL LAURATE Monobutyl maleate Methanol FATTY ACID METHYL ESTER MIX C8-C22 Methyl acrylate Methyl methacrylate Methyl bromide METSULFURON METHYL METHYL OCTADEDANOATE trans-Methyl crotonate

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