p-Bromophenoxyacetic acid

p-Bromophenoxyacetic acid Basic information

Product Name:	p-Bromophenoxyacetic acid
Synonyms:	p-BroMophenoxyacetic;4-BroMophenoxacetic acid;2-(4-bromophenoxy)ethanoic acid;Acetic acid, (4-bromophenoxy)-;Acetic acid, (p-bromophenoxy)-;Acetic acid, (p-bromophenoxy)- (8CI);2-(4-bromophenoxy)acetate;p-Bromophenoxyacetate
CAS:	1878-91-7
MF:	C8H7BrO3
MW:	231.04
EINECS:	217-530-5
Product Categories:	Auxins;Biochemistry;Plant Growth Regulators;C8;Carbonyl Compounds;Carboxylic Acids;Drug Intermediates;Acetics acid and esters;Organic acids;PLANT GROWTH REGULATOR
Mol File:	1878-91-7.mol

p-Bromophenoxyacetic acid Chemical Properties

Melting point	149-153 °C(lit.)
Boiling point	337.9±17.0 °C(Predicted)
density	1.6494 (rough estimate)
refractive index	1.4730 (estimate)
storage temp.	Sealed in dry,Room Temperature
solubility	soluble in Methanol
pka	3.09±0.10(Predicted)
form	powder to crystal
color	White to Almost white
CAS DataBase Reference	1878-91-7(CAS DataBase Reference)
EPA Substance Registry System	Acetic acid, (4-bromophenoxy)- (1878-91-7)

Safety Information

Hazard Codes	Xi
Safety Statements	24/25
WGK Germany	3
TSCA	Yes
HazardClass	IRRITANT
HS Code	29189900

MSDS Information

Provider	Language
(4-Bromophenoxy)acetic acid	English
SigmaAldrich	English
ACROS	English

p-Bromophenoxyacetic acid Usage And Synthesis

Chemical Properties	White or cream crystalline powder
Uses	4-Bromophenoxyacetic acid may be used as a starting material in the preparation of radioiodinated phenoxyacetic acid derivatives with potential application as radiopharmaceuticals.
General Description	4-Bromophenoxyacetic acid, also known as p-bromophenoxyacetate, is a phenoxyalkanoic acid derivative. It is a chemical elicitor that can induce β-glucuronidase (GUS) activity in rice.
Purification Methods	Crystallise the acid from EtOH or H2O (m 161.4-161.8o). [Hayes & Branch J Am Chem Soc 65 1555 1943, Beilstein 6 III 747, 6 IV 1052.]

p-Bromophenoxyacetic acid Preparation Products And Raw materials

Raw materials	4-bromophenyl 2-(4-bromophenoxy)acetate-->Methyl-(4-bromophenoxy)acetate-->Bromoacetic acid-->Iodobenzene-->Ethyl phenoxyacetate-->4-Bromophenol-->Sodium chloroacetate-->Chloroacetic acid-->Phenoxyacetic acid-->Iodine-->Acetic acid
Preparation Products	(4-BROMOPHENOXY)ACETIC ACID ETHYL ESTER

Allyl phenoxyacetate p-Bromophenoxyacetic acid 2,4-DIBROMOPHENOXYACETIC ACID 1-Bromo-4-tert-butylbenzene AKOS B013788 4'-Bromopropiophenone (4-BROMO-2-FORMYL-6-METHOXY-PHENOXY)-ACETIC ACID ETHYL ESTER ETHYL 2-(4-BROMO-2-[(HYDROXYIMINO)METHYL]-6-METHOXYPHENOXY)ACETATE Ascoric Acid Phenoxyacetic acid AKOS B005896 Stearic acid Folic acid [(5,7-dibromoquinolin-8-yl)oxy]acetic acid ETHYL 2-(4-BROMO-2-([(4-CHLOROPHENYL)IMINO]METHYL)-6-METHOXYPHENOXY)ACETATE ETHYL 2-(4-BROMO-2-([(3-CHLOROPHENYL)IMINO]METHYL)-6-METHOXYPHENOXY)ACETATE 4-Chlorophenoxyacetic acid Fluroxypyr

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