4-Fluorothiophenol

4-Fluorothiophenol Basic information

Product Name:	4-Fluorothiophenol
Synonyms:	P-FLUOROTHIOPHENOL;P-FLUOROPHENYL MERCAPTAN;4-FLUOROTHIOPHENOL;4-FLUOROBENZENE-1-THIOL;Fluorothiophenol2;4-FLUOROBENZENETHIOL,98%;4-Fluorothiophenol,98+%;4-Fluoromercaptobenzene
CAS:	371-42-6
MF:	C6H5FS
MW:	128.17
EINECS:	206-737-6
Product Categories:	Fluorobenzene;Phenol&Thiophenol&Mercaptan;Miscellaneous
Mol File:	371-42-6.mol

4-Fluorothiophenol Chemical Properties

Melting point	43-46°C
Boiling point	164-168 °C
density	1.203 g/mL at 25 °C (lit.)
refractive index	n20/D 1.550(lit.)
Fp	130 °F
storage temp.	Keep in dark place,Inert atmosphere,2-8°C
solubility	soluble in Chloroform, Methanol
pka	6.40±0.10(Predicted)
form	Liquid
Specific Gravity	1.203
color	Clear colorless to light yellow
Water Solubility	Not miscible or difficult to mix in water.
Sensitive	Stench
BRN	1446350
InChIKey	OKIHXNKYYGUVTE-UHFFFAOYSA-N
CAS DataBase Reference	371-42-6(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi,F
Risk Statements	10-36/37/38
Safety Statements	26-36-45-16-7/9
RIDADR	UN 3336 3/PG 3
WGK Germany	3
F	9-13-23
Hazard Note	Irritant/Stench
TSCA	N
HazardClass	3
PackingGroup	III
HS Code	29309070

MSDS Information

Provider	Language
4-Mercaptofluorobenzene	English
SigmaAldrich	English
ACROS	English
ALFA	English

4-Fluorothiophenol Usage And Synthesis

Chemical Properties	clear colorless to light yellow liquid
Uses	It is used in the synthesis of Bicalutamide, an anti-cancer drug.
Definition	ChEBI: 4-Fluorothiophenol is a thiol.

4-Fluorothiophenol Preparation Products And Raw materials

Raw materials

Sodium hydroxide-->Dichloromethane-->Chloroform-->Hexane-->Sodium borohydride-->Isopropyl alcohol-->Chlorosulfonic acid-->Sodium thiosulfate-->Fluorobenzene-->Iodotrimethylsilane-->2,1,3-Benzoxadiazole-4-thiol, 7-nitro--->METHYL METHYLPHOSPHONIC ACID-->Di-4-fluorophenyl sulfide-->(4-FLUOROPHENYLTHIO)ACETIC ACID-->4-Fluorobenzenesulfonyl chloride-->METHYLPHOSPHONICACIDETHYLMETHYLESTER-->TRIPHENYLPHOSPHINE SULFIDE

Preparation Products

1-FLUORO-4-(TRIFLUOROMETHYLTHIO)BENZENE-->Bicalutamide

4-Bromo-3-fluorothiophenol 3-CHLORO-5-FLUOROTHIOPHENOL 4-Bromo-2-fluorothiophenol AKOS B014960 2-(2-CHLORO-4-FLUOROPHENYLTHIO)ACETIC ACID 4-FLUOROTHIOPHENOL POTASSIUM SALT,98%,4-FLUOROTHIOPHENOL POTASSIUM SALT 4-Amino-3-fluorothiophenol PENTAFLUOROPHENYL SULFIDE ABD-F 5-AMINO-2-CHLORO-4-FLUOROTHIOPHENOL 3-Bromo-2-methoxy-5-trifluoromethylpyridine 2-Bromo-5-fluorothiophenol 3-Bromo-4-fluorothiophenol P-FLUOROBENZENESULFONIC ACID, NA SALT 4-FLUOROTHIOPHENOL POTASSIUM CHLORIDE 2-Bromo-4-fluorothiophenol SODIUM THIOPHENOXIDE BARIUM PENTAFLUOROBENZENESULFONATE

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