Stannous octoate

Stannous octoate Basic information
Product Name:Stannous octoate
Synonyms:2-ethyl-hexanoicacitin(2++)salt;STANNOUS 2-ETHYLHEXANOATE;STANNOUS 2-ETHYLHEXOATE;STANNOUS CAPRYLATE;Stannous octanoate;STANNOUS OCTOATE;TIN 2-ETHYL HEXANOATE;TIN 2-ETHYLHEXOATE
CAS:301-10-0
MF:C16H30O4Sn
MW:405.12
EINECS:206-108-6
Product Categories:curing agent;Organic-metal salt;metal carboxylate
Mol File:301-10-0.mol
Stannous octoate Structure
Stannous octoate Chemical Properties
Melting point <-20°C
Boiling point >200°C
density 1.251 g/mL at 25 °C(lit.)
vapor pressure 0.3Pa at 20℃
refractive index n20/D 1.493(lit.)
Fp >110°C
pka5.09[at 20 ℃]
form liquid
color viscous
Specific Gravity1.251
Water Solubility Miscible with water.
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Exposure limitsACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
InChIKeyKSBAEPSJVUENNK-UHFFFAOYSA-L
LogP2.64 at 25℃
CAS DataBase Reference301-10-0(CAS DataBase Reference)
EPA Substance Registry SystemStannous 2-ethylhexanoate (301-10-0)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-62-52/53-43-41-63
Safety Statements 26-36/37/39-61
WGK Germany 1
RTECS MO7870000
TSCA Yes
PackingGroup III
HS Code 29159000
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Stannous octoate Usage And Synthesis
Chemical PropertiesWhite or light yellowish brown paste. Soluble in petroleum ether, insoluble in water. low toxicity of Stannous octoate, oral acute poisoning data of rats LD50=3400mg/kg. acute percutaneous poisoning data of rabbits LD50>2000mg/kg.
UsesStannous octoate is susceptible to hydrolysis and oxidation and cannot be used in combination polyethers (premixes). Its catalytic activity is higher than that of dibutyltin dilaurate.
Stannous octoate can be used as a catalyst for polyurethane, mainly in the production of soft block polyether type polyurethane foam, but also as a catalyst for polyurethane coatings, elastomers, room temperature curing silicone rubber, etc. As it is a divalent tin compound, it may be oxidized to tetravalent tin compound itself after foaming, and it remains in the foam body to play the role of an antioxidant, which stays in the foam after foaming and has no adverse effect on the foam performance.
UsesTin(II) 2-ethylhexanoate is used as a polymerization initiator in polylactic acid production. It acts as an intermediate as well as a catalyst for urethane foams, lubricants, addition agents and stabilizers for transformer oils.
UsesA catalyst for polylactide polymerization.
PreparationStannous octoate is produced by reacting 2-ethylhexanoic acid with sodium hydroxide to form sodium 2-ethylhexanoate, which then undergoes a complex decomposition reaction with stannous chloride by heating in an inert solvent.
HazardToxic material.
Flammability and ExplosibilityNonflammable
ToxicologyStannous octoate has influence to human health. It may cause an allergic skin reaction, and serious eye damage. In addition, it is suspected of damaging fertility or the unborn child, and harmful to aquatic life with long lasting effects.
Stannous octoate Ethanol Sodium 2-ethylhexanoate Aluminium 2-ethylhexanoate Tin Ethylbenzene Ethylparaben 6-Aminocaproic acid CHLOROETHANE Ethyl Hexanoate 2-Ethylhexanoic acid Ethyl cellulose Methyl hexanoate Diethyl ether Ethyl acetate Hexyl hexanoate Ethyl acrylate Allyl hexanoate

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