ChemicalBook Product Catalog Chemical Reagents Organic reagents Thiolate 4-(tert-Butyl)benzyl mercaptan

4-(tert-Butyl)benzyl mercaptan

4-(tert-Butyl)benzyl mercaptan Basic information
Product Name:4-(tert-Butyl)benzyl mercaptan
Synonyms:4-tert-Butylbenzylthiol;4-TERT-BUTYLBENZYL MERCAPTAN;[4-(TERT-BUTYL)PHENYL]METHANETHIOL;4-tert-Butylbenzylmercaptane;4-(1,1-DIMETHYLETHYL)BENZENEMETHANETHIOL;P-TERT-BUTYLBENZYL THIOL;4-tert-Butylbenzenemethanethiol;tert-Butylbenzyl Mercapt
CAS:49543-63-7
MF:C11H16S
MW:180.31
EINECS:
Product Categories:Organic Building Blocks;Sulfur Compounds;Thiols/Mercaptans
Mol File:49543-63-7.mol
4-(tert-Butyl)benzyl mercaptan Structure
4-(tert-Butyl)benzyl mercaptan Chemical Properties
Boiling point 102-103 °C3.1 mm Hg(lit.)
density 0.966 g/mL at 25 °C(lit.)
refractive index n20/D 1.5430(lit.)
Fp 162 °F
pka9.83±0.10(Predicted)
form clear liquid
color Colorless to Light yellow to Light orange
CAS DataBase Reference49543-63-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN 3334
WGK Germany 3
HS Code 2930909899
MSDS Information
ProviderLanguage
SigmaAldrich English
4-(tert-Butyl)benzyl mercaptan Usage And Synthesis
Chemical PropertiesColorless or light yellow liquid
Uses4-tert-Butylbenzyl mercaptan (BBSH) may be used in the preparation of N-Me-aminopyrimidinone derivatives, which are potent state-dependent inhibitor of Nav1.7 (Nav= voltage-gated sodium channel). It may also be used to synthesize organic-soluble, atomically precise array of silver clusters via a novel approach based on the miscibility principle while avoiding the use of phase-transfer agents.
General Description4-tert-Butylbenzyl mercaptan is a benzyl mercaptan derivative that is commonly used as a ligand for synthesizing metal clusters.
4-(tert-Butyl)benzyl mercaptan Preparation Products And Raw materials
Raw materialsSodium hydrosulfide-->Tetrabutylammonium bromide-->Benzene,1-(1,1-dimethylethyl)-4-(methylthio)-->4-TERT-BUTYLBENZYL ALCOHOL-->4-tert-Butylbenzaldehyde
Preparation ProductsDI-N-OCTYL DISULFIDE
4-(tert-Butyl)benzyl mercaptan tert-Butylhydroquinone Benzyl mercaptan 4-tert-Butylcatechol 5-([4-(TERT-BUTYL)BENZYL]SULFONYL)-1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE-4-CARBONITRILE Cyhalofop-butyl 4-tert-Butylphenol 4-t-Butylbenzamide Butylated hydroxyanisole Benzyl alcohol Buprofezin 4-tert-Butylbenzoyl chloride Methyl 4-tert-butylbenzoate METHYL MERCAPTAN Dibutyl phthalate BUTYL OLEATE Benzyl 4-tert-Butyl-2-nitrophenol
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