1-ETHYNYL-2-FLUOROBENZENE

1-ETHYNYL-2-FLUOROBENZENE Basic information
Product Name:1-ETHYNYL-2-FLUOROBENZENE
Synonyms:1-Ethynyl-2-fluorobenzene,97%;Benzene, 1-ethynyl-2-fluoro-;2-Fluorophenylacetylene 97%;1-Ethynyl-2-fluorobenzene, 97% 1GR;1-Ethynyl-2-fluorobenzene, 97% 250MG;2'-FLUOROPHENYL ACETYLENE;2-FLUOROPHENYLACETYLENE;1-ETHYNYL-2-FLUOROBENZENE
CAS:766-49-4
MF:C8H5F
MW:120.12
EINECS:
Product Categories:Organic Fluorinated Building Blocks;Other Fluorinated Organic Building Blocks;Acetylenes;Acetylenic Hydrocarbons having Benzene Ring;Alkynyl;Halogenated Hydrocarbons;Organic Building Blocks;Alkynyl Fluorinated Building Blocks;Building Blocks;Chemical Synthesis;Fluorinated Building Blocks;Halogenated Hydrocarbons;Organic Building Blocks
Mol File:766-49-4.mol
1-ETHYNYL-2-FLUOROBENZENE Structure
1-ETHYNYL-2-FLUOROBENZENE Chemical Properties
Boiling point 150 °C (lit.)
density 1.06 g/mL at 25 °C (lit.)
refractive index 1.524-1.527
Fp 37 °C
storage temp. 2-8°C
form Liquid
color Clear yellow to brownish
CAS DataBase Reference766-49-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-10
Safety Statements 37/39-26-16-36
RIDADR UN 1993 3/PG 3
WGK Germany 3
Hazard Note Irritant
HazardClass 3
PackingGroup III
HS Code 29039990
MSDS Information
ProviderLanguage
ACROS English
1-ETHYNYL-2-FLUOROBENZENE Usage And Synthesis
Chemical Propertiesclear yellow to brownish liquid
UsesEmployed in studies on the polymerization1 and cross-coupling2 of phenylacetylenes.
Uses1-Ethynyl-2-fluorobenzene has been employed in the cross-coupling of phenylacetylenes. It may be used in the preparation of 3-(2-deoxy-β-D-ribofuranosyl)-6-(2-fluorophenyl)-2,3-dihydrofuro-[2,3-d]pyrimidin-2-one and 4-(2-fluorophenylethynyl)-3-methyl-5-phenylisoxazole.
Application1-Ethynyl-2-fluorobenzene has been employed in the cross-coupling of phenylacetylenes. It may be used in the preparation of 3-(2-deoxy-β-D-ribofuranosyl)-6-(2-fluorophenyl)-2,3-dihydrofuro-[2,3-d]pyrimidin-2-one and 4-(2-fluorophenylethynyl)-3-methyl-5-phenylisoxazole.1-Ethynyl-2-fluorobenzene, a fluorinated benzene derivative, is a terminal alkyne.
General Description1-Ethynyl-2-fluorobenzene, a fluorinated benzene derivative, is a terminal alkyne.
1-ETHYNYL-2-FLUOROBENZENE Preparation Products And Raw materials
Preparation Products2-Fluorostyrene-->2'-Fluoroacetophenone-->Benzenepropanenitrile, 2-fluoro-
3-(4-CHLORO-2-FLUOROPHENYL)-2-PROPYN-1-OL 1-ETHYNYL-2-FLUOROBENZENE 2-([3-(2,4-DIFLUOROPHENYL)PROP-2-YNYL]OXY)TETRAHYDRO-2H-PYRAN 3-(2-FLUORO-PHENYL)-PROP-2-YN-1-OL 1-[2-(4-BROMOPHENYL)ETHYNYL]-2-FLUORO-4-PENTYLBENZENE 4-(2,4-DIFLUOROPHENYL)-3-BUTYN-2-OL 4-(2,5-DIFLUOROPHENYL)-2-METHYL-3-BUTYN-2-OL 3-(2,5-DIFLUOROPHENYL)-2-PROPYN-1-OL (2-FLUORO-PHENYL)-PROPYNOIC ACID ETHYL ESTER 4-(2,5-DIFLUOROPHENYL)-3-BUTYN-2-OL 4-(2-FLUOROPHENYL)-2-METHYL-3-BUTYN-2-OL 4-(2,4-DIFLUOROPHENYL)-2-METHYL-3-BUTYN-2-OL (2-FLUOROPHENYLETHYNYL)TRIMETHYLSILANE 4-(2-FLUOROPHENYL)-3-BUTYN-2-OL (2,4-DIFLUOROPHENYLETHYNYL)TRIMETHYLSILANE AKOS B029844 3-(2,4-DIFLUOROPHENYL)-2-PROPYN-1-OL 1-ETHYNYL-2.4-DIFLUOROBENZENE 97

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