9,9-Bis(4-hydroxyphenyl)fluorene

9,9-Bis(4-hydroxyphenyl)fluorene Basic information
The monomers and modifiers of functional polymer material Uses
Product Name:9,9-Bis(4-hydroxyphenyl)fluorene
Synonyms:9,9-BIS(4-HYDROXYPHENYL)FLUORENE;4,4'-(9-FLUORENYLIDENE)DIPHENOL;fluorene-9-bispheno;phenol,,4’-(9h-fluoren-9-ylidene)bis;Bisphenol FL;9,9-Bis(Hydroxyphenyl)Fluorene;9-Fluorenebisphenol;BISPHENOLFLUORENE
CAS:3236-71-3
MF:C25H18O2
MW:350.41
EINECS:406-950-6
Product Categories:Fluorenes, Flurenones;Fluorene Derivatives;Phenoles and thiophenoles;Electronic Chemicals;Color Former & Related Compounds;Developer;Fluorenes;Fluorenes & Fluorenones;Fluorenes, etc. (reagent for high-performance polymer research);Functional Materials;Reagent for High-Performance Polymer Research;Fluorene series;API;3236-71-3
Mol File:3236-71-3.mol
9,9-Bis(4-hydroxyphenyl)fluorene Structure
9,9-Bis(4-hydroxyphenyl)fluorene Chemical Properties
Melting point 224-226 °C (lit.)
Boiling point 526.4±50.0 °C(Predicted)
density 1.288±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
Water Solubility Insoluble in water
pka9.58±0.30(Predicted)
form neat
color White to Almost white
BRN 2060986
InChIKeyYWFPGFJLYRKYJZ-UHFFFAOYSA-N
CAS DataBase Reference3236-71-3(CAS DataBase Reference)
EPA Substance Registry SystemPhenol, 4,4'-(9H-fluoren-9-ylidene)bis- (3236-71-3)
Safety Information
Hazard Codes Xi,N
Risk Statements 36/38-50/53-36/37/38
Safety Statements 26-37-60-61-37/39
RIDADR UN 3077 9/PG 3
WGK Germany 2
HazardClass IRRITANT
PackingGroup III
HS Code 38220000
MSDS Information
ProviderLanguage
SigmaAldrich English
9,9-Bis(4-hydroxyphenyl)fluorene Usage And Synthesis
The monomers and modifiers of functional polymer material9,9-Bis(4-hydroxyphenyl)fluorene is the monomer and modifier of functional polymer material,it is Cardo skeleton structure bisphenol compound, it is important monomer and modifier of synthesis of fluorene-based epoxy resin, fluorene and benzene benzoxazine resins, acrylic resins, polyester resins, polycarbonate, epoxy, polyester or polyether condensation products. Fluorene-based epoxy resin has excellent humidity resistance and heat resistance, dielectric properties, mechanical properties, chemical resistance, etc., it has been important monomer and modifier of high-performance resin matrix materials, electronic packaging materials, high temperature resistant adhesives, heat resistant coatings, etc. But the rigidity of fluorene-based epoxy resin is better, but toughness is poor, therefore, it need to be modified toughening when be used, or use the method of mixing with general-purpose epoxy resin to modify.
The above information is edited by the chemicalbook of Wang Xiaodong.
UsesIt can be used the intermediate of organic synthesis.
Chemical PropertiesWhite to tan powder or crystal or chunks
Uses9,9-Bis (4-Hydroxyphenyl) Fluorene is used in the production of polyarylene ethers and extensively used in the study of polymer electrolyte membranes with the potential for fuel cell application.
Uses4,4'-(9-fluorenylidene)diphenol be used for the synthesis of novel poly (arylene ether).
UsesBisphenol FL may be used as an analytical reference standard for the quantification of the analyte in:
  • Human breast milk using gas chromatography-tandem mass spectrometry (GC-MS/MS).
  • Wastewaters and surface water using gas chromatography-mass spectrometry (GC-MS).

DefinitionChEBI: 9,9-bis(4-hydroxyphenyl)fluorene is a member of the class of fluorenes that is 9H-fluorene in which both of the hydrogens at position 9 have been replaced by p-hydroxyphenyl groups. It has a role as an anti-estrogen. It is a member of fluorenes and a polyphenol.
General DescriptionBisphenol FL (BPFL) is a fluorinated derivative of bisphenol (BP), a wide group of chemicals with similar structures, recognized as environmental pollutants. Bisphenol A (BPA), and its structural analogs are widely used as plasticizers and monomers for synthetic materials, industrial and consumer products including fluorine rubber, food container linings, canned food, thermal receipts, etc.
9,9-Bis(4-hydroxyphenyl)fluorene Preparation Products And Raw materials
Preparation ProductsBisphenoxyethanolfluorene
9-Fluorenone 4,4'-Sulphonylbis(2,6-dibromophenol) Phenolic epoxy resin Polyethylene 9,9-Bis[4-(2-acryloyloxyethyloxy)phenyl]fluorene tert-Butanol Sodium carboxymethyl cellulose Bisphenoxyethanolfluorene Polyamide 9,9-Bis(4-hydroxyphenyl)fluorene 2-tert-Butylaniline 9,9-BIS(3-AMINO-4-HYDROXYPHENYL)FLUORENE 2,7-Dibromo-9,9-bis(4-hydroxyphenyl)fluorene Fluorene Biscresolfluorene DIGLYCIDYL-9,9-BIS(4-HYDROXYPHENYL)FLUORENE 9,9-BIS(3',5'-DIBROMO-4'-HYDROXYPHENYL)FLUORENE 9,9-BIS(4-TRIFLUOROVINYLOXYPHENYL)FLUORENE

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