ChemicalBook Product Catalog Organic Chemistry Carboxylic acids and derivatives Cyclic carboxylic acids Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4

Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4

Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4 Basic information
Reactions
Product Name:Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4
Synonyms:Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4;Rh2(S-?BTPCP)?4;Tetrakis[(S)-[(1S)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II)
CAS:1345974-63-1
MF:C88H68Br4O8Rh2
MW:1778.90372
EINECS:
Product Categories:
Mol File:1345974-63-1.mol
Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4 Structure
Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4 Chemical Properties
form solid
color green
CAS DataBase Reference1345974-63-1
Safety Information
MSDS Information
Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4 Usage And Synthesis
Reactions
  1. Chiral catalyst used for the enantioselective formation of cyclopropanes from the reaction of aryls with styryl diazoacetates.
  2. Chiral catalyst used for the asymmetric synthesis of bicyclo[1.1.0]butane rings via the rhodium-catalyzed decomposition of 2-diazo-5-arylpent-4-enoates.
  3. Reaction of vinyldiazoacetates with nitrones to form 2.5-dihydroisooxazoles, 
Reactions of 1345974-63-1
Tetrakis[(S)-(+)-[(1S)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(S-BTPCP)4 Preparation Products And Raw materials
Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(R-PTAD)4 TETRAKIS[(S)-(-)-N-(P-DODECYLPHENYLSULFONYL)PROLINATO]DIRHODIUM(II) TETRAKIS[(R)-(+)-N-(P-DODECYLPHENYLSULFONYL)PROLINATO]DIRHODIUM(II)
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