1-Ethyl-3-methylimidazolium tetrafluoroborate

1-Ethyl-3-methylimidazolium tetrafluoroborate Basic information
Product Name:1-Ethyl-3-methylimidazolium tetrafluoroborate
Synonyms:EMIMBF4;Ethylmethylimidazoliumtetrafluoroborate;formoltensalt;1-ETHYL-3-METHYL-1 H-IMIDAZOLIUM TETRAFLUOROBORATE;1-ETHYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE;1-Ethyl-3-methylimidazolium tetrafluoroborate, 98+%;1-Ethyl-3-methylimidazolium Tetrafluoroborate [for Molten Salt];1-Ethyl-3-methylimidazolium tetrafluoroborate ,99%
CAS:143314-16-3
MF:C6H11BF4N2
MW:197.97
EINECS:671-177-5
Product Categories:Ionic liquid;B (Classes of Boron Compounds);Imidazolium Compounds;Imidazolium Salts (Ionic Liquids);Ionic Liquids;Synthetic Organic Chemistry;Tetrafluoroborates
Mol File:143314-16-3.mol
1-Ethyl-3-methylimidazolium tetrafluoroborate Structure
1-Ethyl-3-methylimidazolium tetrafluoroborate Chemical Properties
Melting point 15 °C (lit.)
Boiling point >350 °C (lit.)
density 1.294 g/mL at 25 °C (lit.)
vapor pressure 0-0Pa at 20-25℃
refractive index n20/D 1.413(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
form liquid
color Colorless to Light orange to Yellow
Sensitive Hygroscopic
InChIInChI=1S/C6H11N2.BF4/c1-3-8-5-4-7(2)6-8;2-1(3,4)5/h4-6H,3H2,1-2H3;/q+1;-1
InChIKeyRNBAQXLNJMVTCI-UHFFFAOYSA-M
SMILES[B-](F)(F)(F)F.N1(CC)C=C[N+](C)=C1
CAS DataBase Reference143314-16-3(CAS DataBase Reference)
ECW3.6 - 4.0 V
Safety Information
Hazard Codes Xn,N
Risk Statements 36/38-51/53-22-24/25-23
Safety Statements 23-24/25-61
RIDADR UN3082 9/PG 3
WGK Germany 3
3-10
HazardClass 8
PackingGroup III
HS Code 29332900
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
1-Ethyl-3-methylimidazolium tetrafluoroborate Usage And Synthesis
Conductivity14.1 mS/cm (25 °C)
Chemical PropertiesLight yellow liquid
Uses1-Ethyl-3-methylimidazolium tetrafluoroborate is a room temperature ionic liquid widely used as an electrolyte in electrochemical studies. Its diffusion coefficient, 13C spin-lattice relaxation times, and nuclear Overhauser enhancements have been analyzed using NMR techniques to study its hydrogen bonding. Some of its fundamental physical and chemical properties such as density, viscosity, thermal stability, surface tension, refractive index and pH have been studied over a wide range of temperature.
UsesThe enzymatic resolution of homophenylalanine ester to form enantiomeric homophenylalanine can be performed using 1-ethyl-3-methylimidazolium tetrafluoroborate as a reaction medium.
Uses1-Ethyl-3-methylimidazolium tetrafluoroborate is an ionic liquid used in the recycling of osmium in the dihydroxylation of olefins with osmium(VIII)? oxide. It is a stable liquid electrolyte used in the capillary electrophoretic method for resolving phenolic compounds present in grape seed extract. It also acts as a good solvent for a wide range of both organic and inorganic compounds.
General Description1-Ethyl-3-methylimidazolium tetrafluoroborate is an air and water stable, room temperature ionic liquid (RTIL). It can be prepared by reacting 1-ethyl-3-methylimidazolium bromide with tetrafluoroboric acid.
1-Ethyl-3-methylimidazolium tetrafluoroborate 1-BENZYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE 1-BUTYL-2,3-DIMETHYLIMIDAZOLIUM TETRAFLUOROBORATE 1,3-Bis(1-adamantyl)imidazolium tetrafluoroborate 1,3-DIALLYLIMIDAZOLIUM TETRAFLUOROBORATE 1-ALLYL-3-BUTYLIMIDAZOLIUM TETRAFLUOROBORATE 1-DECYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE 3-METHYL-1-TETRADECYLIMIDAZOLIUM TETRAFLUOROBORATE RARECHEM AQ NN 0054 AZURE B TETRAFLUOROBORATE 1,3-Diisopropylimidazolium tetrafluoroborate 1-ETHYL-2,3-DIMETHYLIMIDAZOLIUM TETRAFLUOROBORATE ISOXADIFEN-ETHYL 1 3-DI-TERT-BUTYLIMIDAZOLIUM TETRAFLUORO 2-Ethoxyethanol 1-ALLYL-3-ETHYLIMIDAZOLIUM TETRAFLUOROBORATE 1,3-DICYCLOHEXYL-IMIDAZOLIUM TETRAFLUOROBORATE 1-HEXYL-2,3-DIMETHYLIMIDAZOLIUM TETRAFLUOROBORATE

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