Phosphoric acid tris(2-chloro-1-methylethyl) ester

Phosphoric acid tris(2-chloro-1-methylethyl) ester Basic information
Product Name:Phosphoric acid tris(2-chloro-1-methylethyl) ester
Synonyms:Phosphoric acid tris(2-chloro-1-methylethyl) ester;TRIS(1-CHLOROPROPYL)PHOSPHATE;TRIS(CHLOROISOPROPYL)PHOSPHATE;TRIS(MONOCHLOROPROPYL) PHOSPHATE;TcppTris(1-Chloro-2-Propyl)Phosphate];TRIS-(1-CHLORO-2-PROPYL)PHOSPHATE (TCPP);Tri(chloroisopropyl)phosphate;Tris(1-chloro-2-propyl) phosphate, Tris(2-chloroisopropyl) phosphate
CAS:13674-84-5
MF:C9H18Cl3O4P
MW:327.57
EINECS:237-158-7
Product Categories:Organics;13674-84-5
Mol File:13674-84-5.mol
Phosphoric acid tris(2-chloro-1-methylethyl) ester Structure
Phosphoric acid tris(2-chloro-1-methylethyl) ester Chemical Properties
Melting point -39.9°C
Boiling point 270°C
density 1.28
refractive index 1.460~1.466 (20℃/D)
Fp -218 °C
storage temp. Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form liquid
color Clear Colourless
Odormild odor
Water Solubility <0.1 g/100 mL at 19.5 ºC
BRN 1842347
Stability:Moisture Sensitive
InChIKeyKVMPUXDNESXNOH-UHFFFAOYSA-N
CAS DataBase Reference13674-84-5(CAS DataBase Reference)
NIST Chemistry Reference2-Propanol, 1-chloro-, phosphate (3:1)(13674-84-5)
EPA Substance Registry SystemTris(1-chloro-2-propyl) phosphate (13674-84-5)
Safety Information
Hazard Codes Xn
Risk Statements 22-37
WGK Germany 1
RTECS TC9000000
Hazardous Substances Data13674-84-5(Hazardous Substances Data)
MSDS Information
Phosphoric acid tris(2-chloro-1-methylethyl) ester Usage And Synthesis
Chemical PropertiesTris(2-chloro-1-methylethyl) phosphate is clear colorless oily liquid with high water solubility and low lipophilicity (as indicated by logKOW). This substance ismanufactured as a reactionmixture, which contains four isomers. It is the primary isomer in the mixture at 50–85% weight/weight (w/w), followed by bis(1- chloro-2-propyl)-2-chloropropyl phosphate [15–40% (w/w); CASRN: 76025-08-6], bis(2-chloropropyl)-1-chloro-2-propyl phosphate [<15% (w/w); CASRN: 76649-15-5], and tris(2- chloropropyl) phosphate [<1% (w/w); CASRN: 6145-73-9] (EURAR, 2008).
UsesTris(1-chloro-2-propyl) Phosphate is a flame retardant of low hydrolytic stability, used in polyurethane (PU) rigid and flexible foam, PVC, EVA and phenolics and epoxy resin.
UsesTris(1-chloro-2-propyl) Phosphate is a flame retardant of low hydrolytic stability, used in polyurethane (PU) rigid and flexible foam, PVC, EVA, phenolics and epoxy resin.
DefinitionChEBI: Tris(1-chloropropan-2-yl) phosphate is a trialkyl phosphate.
General DescriptionClear colorless viscous liquid. Tris(2-chloroisopropyl) Phosphate(TCPP), mixture of isomers is suitable for use in environmental and food residue analysis. It is a mixture of isomers, composition may vary, typical composition: main isomer tris(1-chloro-2-propyl) phosphate 66%, minor components: bis(1-chloro-2-propyl) (2-chloropropyl) phosphate and (1-chloro-2-propyl) bis(2-chloropropyl) phosphate.
Air & Water ReactionsInsoluble in water.
Reactivity ProfilePhosphoric acid tris(2-chloro-1-methylethyl) ester may hydrolyze under acidic or alkaline conditions.
Health HazardACUTE/CHRONIC HAZARDS: When heated to decomposition Phosphoric acid tris(2-chloro-1-methylethyl) ester emits very toxic fumes.
Fire HazardPhosphoric acid tris(2-chloro-1-methylethyl) ester is probably combustible.
Phosphoric acid tris(2-chloro-1-methylethyl) ester Preparation Products And Raw materials
Calcium phosphate monobasic Tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphate Tris(triphenylphosphine)rhodiu TRIXYLYL PHOSPHATE Diphenyl isopropylphenyl phosphate Tris(1,3-dichloro-2-propyl)phosphate Potassium Phosphate Dibasic Aluminum dihydrogen phosphate Isopropylphenyl phosphate TRI-(P-TERT-BUTYLPHENYL) PHOSPHATE Potassium phosphate tribasic Triisobutyl phosphate MAGNESIUM PHOSPHATE Sodium polyacrylate Tris(monochloropropyl) phosphate Phosphoric acid tris(2-chloro-1-methylethyl) ester TRIS (1,3-DICHLORO-2-PROPYL) PHOSPHATE, [PROPYL-2-14C] TRIS-(1,3-DICHLORO-2-PROPYL)PHOSPHATE, [1-3-14C]-

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