|
| | 2-Amino-4-methoxy-6-methylpyrimidine Basic information |
| | 2-Amino-4-methoxy-6-methylpyrimidine Chemical Properties |
| Melting point | 156-158 °C (lit.) | | Boiling point | 255.11°C (rough estimate) | | density | 1.2081 (rough estimate) | | refractive index | 1.6500 (estimate) | | solubility | methanol: soluble1%, clear to very slightly hazy, colorless to yellow | | form | powder to crystal | | pka | 6.38±0.10(Predicted) | | color | White to Almost white | | BRN | 121733 | | CAS DataBase Reference | 7749-47-5(CAS DataBase Reference) |
| | 2-Amino-4-methoxy-6-methylpyrimidine Usage And Synthesis |
| Chemical Properties | white to pinkish or light beige | | Uses | 2-Amino-4-methoxy-6-methylpyrimidine may be employed as nucleophile to investigate the regioselective introduction of some nucleophiles at the secondary position of Baylis-Hillman adducts. It may be used in the preparation of 2-amino-4-methoxy-6-methylpyrimidin-1-ium picrate. | | General Description | 2-Amino-4-methoxy-6-methylpyrimidine (AMMP) is a pyrimidine derivative. It acts as electron donor and forms charge transfer complexes with iodine (σ-electron acceptor). The FTIR and FT-Raman spectra of 2-amino-4-methoxy-6-methylpyrimidine have been recorded to evaluate the energy, structural and thermodynamical parameters. Molecules of AMMP exhibit space group of Pnma and are joined by two N-H…N hydrogen bonds. | | Purification Methods | Recrystallise it from H2O. The picrate has m 220-221o(dec). [Baker et al. J Am pKEst ~ Chem Soc 69 3072, 3075 1947, Sirakawa et al. Yakugaku Zasshi 73 598 1953, Backer & Grevenstuk Recl Trav Chim, Pays-Bas 61 291 1942, Beilstein 25 III/IV 3385.] |
| | 2-Amino-4-methoxy-6-methylpyrimidine Preparation Products And Raw materials |
|
