ChemicalBook Product Catalog Flavors and fragrances Synthetic fragrances Carboxylic acids and esters Aliphatic dicarboxylic acid esters cis-3-Hexenyl formate

cis-3-Hexenyl formate

cis-3-Hexenyl formate Basic information
Product Name:cis-3-Hexenyl formate
Synonyms:BETA, GAMMA-HEXENYL METHANOATE;C3 HEXENYL FORMATE;FEMA 3353;FORMIC ACID CIS-3-HEXEN-1-YL ESTER;CIS-3-HEXEN-1-YL FORMATE;CIS-3-HEXENYL FORMATE;(Z)-3-HEXENOL FORMATE;(Z)-3-HEXENYL FORMATE
CAS:33467-73-1
MF:C7H12O2
MW:128.17
EINECS:251-532-7
Product Categories:Alphabetical Listings;Flavors and Fragrances;G-H
Mol File:33467-73-1.mol
cis-3-Hexenyl formate Structure
cis-3-Hexenyl formate Chemical Properties
Melting point -62.68°C (estimate)
Boiling point 72 °C/40 mmHg (lit.)
density 0.91 g/mL at 25 °C(lit.)
FEMA 3353 | CIS-3-HEXENYL FORMATE
refractive index n20/D 1.426(lit.)
Fp 113 °F
Odorat 10.00 % in dipropylene glycol. fresh green waxy sweet vegetable grassy sharp
Odor Typegreen
JECFA Number1272
LogP2.10
CAS DataBase Reference33467-73-1(CAS DataBase Reference)
NIST Chemistry Reference3-Hexen-1-ol, formate, (z)-(33467-73-1)
EPA Substance Registry System3-Hexen-1-ol, formate, (3Z)- (33467-73-1)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/38
Safety Statements 16-26-36
RIDADR UN 3272 3/PG 3
WGK Germany 2
RTECS MP8550000
MSDS Information
ProviderLanguage
SigmaAldrich English
cis-3-Hexenyl formate Usage And Synthesis
Descriptioncis-3-Hexenyl formate has a light topnote and a fruity fresh odor.
Chemical Propertiescis-3-Hexneyl formate has a light top note and a fruity fresh odor.
Chemical Properties(Z)-3-Hexenyl Formate has been identified in tea. It possesses a green, fruity odor and is used in perfumery and flavor compositions to impart fruity, green notes.
OccurrenceReported found in raspberry, corn mint oil, black tea, mango, corn oil and black chokeberry.
DefinitionChEBI: Cis-3-Hexenyl formate is a carboxylic ester.
Taste threshold valuesTaste characteristics at 20 ppm: green, waxy, fresh, vegetable, fruity, apple, guava and green banana
General Descriptioncis-3-Hexenyl formate is a flavor and fragrance ester mainly used for its green notes. It occurs naturally in gardenia and zinchoge flowers.
cis-3-Hexenyl formate Preparation Products And Raw materials
Raw materials(-)-MENTHYL CHLOROFORMATE-->Leaf alcohol
Preparation Products2(3H)-Furanone, dihydro-3-propyl-
cis-3-Hexenyl formate cis-3-Hexenyl lactate PYRUVIC ACID CIS-3-HEXEN-1-YL ESTER cis-3-Hexenyl hexanoate O-ACETYLRICINOLEIC ACID METHYL ESTER cis-3-Hexenyl tiglate FEMA 3498 N-VALERIC ACID CIS-3-HEXEN-1-YL ESTER cis-3-Hexenyl 2-methylbutanoate 1,2-dihydro-3,4,5,6-tetraphenylphthalic anhydride CIS-3-HEXENYL BUTYRATE cis-3-Hexenyl phenylacetate CIS-3-HEXENYL PROPIONATE (1S,5R)-(-)-2-OXABICYCLO[3.3.0]OCT-6-EN-3-ONE cis-3-Hexenyl benzoate CIS-3-HEXENYL ACETATE CIS-3-HEXENYL ISOBUTYRATE CINNAMIC ACID CIS-3-HEXEN-1-YL ESTER
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