ETHYL 2-OXO-1-CYCLOOCTANECARBOXYLATE

ETHYL 2-OXO-1-CYCLOOCTANECARBOXYLATE Basic information
Product Name:ETHYL 2-OXO-1-CYCLOOCTANECARBOXYLATE
Synonyms:Ethyl 2-oxo-1-cyclooctane-carboxylate, 98+%;Cyclooctanecarboxylic acid, 2-oxo-, ethyl ester;ETHYL 2-OXO-1-CYCLOOCTANECARBOXYLATE;Ethyl 2-oxo-1-cyclooctanecarboxylate 97%;ethyl2-oxocyclooctane-1-carboxylate
CAS:4017-56-5
MF:C11H18O3
MW:198.26
EINECS:
Product Categories:Building Blocks;C10 to C11;C10 to C11;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Carbonyl Compounds;Esters
Mol File:4017-56-5.mol
ETHYL 2-OXO-1-CYCLOOCTANECARBOXYLATE Structure
ETHYL 2-OXO-1-CYCLOOCTANECARBOXYLATE Chemical Properties
Boiling point 85-87 °C/0.1 mmHg (lit.)
density 1.04 g/mL at 25 °C (lit.)
refractive index n20/D 1.483(lit.)
Fp >230 °F
pka12.32±0.20(Predicted)
form Liquid
color Clear colorless
CAS DataBase Reference4017-56-5
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 29183000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ETHYL 2-OXO-1-CYCLOOCTANECARBOXYLATE Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesEthyl 2-oxo-1-cyclooctanecarboxylate (2-carbethoxycyclooctanone) may be used in the synthesis of 2-carbethoxy-2-cyclooctenone.
General DescriptionEthyl 2-oxo-1-cyclooctanecarboxylate (2-carbethoxycyclooctanone) is a β-keto ester. It undergoes Michael addition with 3-buten-2-one (methyl vinyl ketone, MVK) in the presence of potassium bis(1,2-benzenediolato)phenylsilicate to afford the corresponding 1,4-adduct. It can be synthesized from cycloheptanone. Its boiling point, density and refractive index have been determined.
ETHYL 2-OXO-1-CYCLOOCTANECARBOXYLATE Preparation Products And Raw materials
ETHYL 2-OXO-1-CYCLOOCTANECARBOXYLATE Pentanoic acid, 2-ethyl-3-oxo-, methyl ester 3-KETO-2-PROPYLPENTANOIC ACID ETHYL ESTER 2-METHYL-3-OXO-PENTANOIC ACID ETHYL ESTER Ethyl 2-propylacetoacetate METHYL 3-KETOOCTANOATE 2-METHYL-3-OXO-HEXANOIC ACID ETHYL ESTER 3-OXOENANTHIC ACID ETHYL ESTER 2-n-propyl-3-oxopentanoic acid CYCLOOCTANONE Ethyl 2-pentylacetoacetate Cyclooctane SALOR-INT L166731-1EA Cyclooctanecarbaldehyde SALOR-INT L161314-1EA Ethyl 2-acetylhexanoate Methyl 2-pentylacetoacetate CYCLOOCTANEMETHANOL

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