GERMANIUM TETRABROMIDE

GERMANIUM TETRABROMIDE Basic information
Description References
Product Name:GERMANIUM TETRABROMIDE
Synonyms:Germane,tetrabromo-;germylbromide;tetrabromo-german;GERMANIUM BROMIDE;GERMANIUM BROMIDE (IV);GERMANIUM (IV) BROMIDE;GERMANIUM TETRABROMIDE;tetrabromogermane
CAS:13450-92-5
MF:Br4Ge
MW:392.26
EINECS:236-612-1
Product Categories:metal halide;Catalysis and Inorganic Chemistry;Chemical Synthesis;Germanium Salts;GermaniumMetal and Ceramic Science;Salts;Catalysis and Inorganic Chemistry;Chemical Synthesis;Germanium;Germanium Salts;Materials Science;Metal and Ceramic Science
Mol File:13450-92-5.mol
GERMANIUM TETRABROMIDE Structure
GERMANIUM TETRABROMIDE Chemical Properties
Melting point 26.1 °C(lit.)
Boiling point 186.5 °C(lit.)
density 3.13 g/mL at 25 °C(lit.)
refractive index 1.6269
Fp 186.5°C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Low Melting Solid/Liquid, Ampouled Under Argon
color White to gray
Specific Gravity3.132
Water Solubility It reacts in water.
Sensitive Moisture Sensitive
Stability:Stable. Incompatible with water, strong oxidizing agents.
CAS DataBase Reference13450-92-5(CAS DataBase Reference)
EPA Substance Registry SystemGermane, tetrabromo- (13450-92-5)
Safety Information
Hazard Codes C
Risk Statements 14-34-37
Safety Statements 26-27-36-45-36/37/39
RIDADR UN 3260 8/PG 2
WGK Germany 3
RTECS LY5220000
TSCA Yes
HazardClass 8
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
GERMANIUM TETRABROMIDE Usage And Synthesis
DescriptionGermanium (IV) bromide is a white solid with acidic smell. It reacts violently with water. It is soluble in pure ethanol, carbon tetrachloride, benzene and ether.1 It is used as a germanium source for uses compatible with bromides and in acidic condition. It is used as a chemical gent.2
References
  1. https://de.wikipedia.org/wiki/Germanium(IV)-bromid
  2. D. C. Ayres, D. G. Hellier, Dictionary of Environmentally Important Chemicals, 1998, ISBN 0-7514-0256-7
Chemical Propertiessolid ingot in glass with 99.999% purity; white crystal(s); enthalpy of vaporization 41.4 kJ/mol; can be prepared readily by reacting Ge with Br2 or with GeO2 and HBr solutions [KIR78] [STR93] [CER91] [CRC10]
UsesIt is used as a chemical agent, as a laboratory chemical & for manufacturing of substances.
Safety ProfilePoison by intravenous route. When heated to decomposition it emits very toxic fumes of Br-. See also GERMANIUM COMPOUNDS.
Purification MethodsPurify it by simple distillation or fractionation depending on purity. It is soluble in EtOH, CHCl3, *C6H6 and Et2O. It fumes in moist air and is readily hydrolysed by water. [Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 718 1963]. LACHRYMATORY.
GERMANIUM TETRABROMIDE Preparation Products And Raw materials
Preparation ProductsGERMANIUM DIBROMIDE-->GERMANIUM(IV) CHLORIDE
TETRA-N-BUTYLGERMANE TRIPHENYLGERMANIUM CHLORIDE Tetramethylgermane TRIMETHYLGERMANIUM CHLORIDE DIMETHYLGERMANIUM DICHLORIDE TRIETHYLGERMANIUM CHLORIDE GERMANIUM (II) SULFIDE GERMANIUM TETRAIODIDE GERMANIUM(IV) ETHOXIDE TETRAETHYLGERMANE GERMANIUM CHLORIDE DIOXANE COMPLEX (1:1) Germanium oxide GERMANIUM(II) IODIDE DIETHYLGERMANIUM DICHLORIDE GERMANIUM SELENIDE GERMANIUM TETRABROMIDE GERMANIUM DIBROMIDE Germanium Germanium Bromide

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