Empenthrin

Empenthrin Basic information
Product Name:Empenthrin
Synonyms:1-ETHINYL-2-METHYL-2-PENTEN-1-YL CHRYSANTHEMATE;D-EMPENTHRIN;[(E)-4-methylhept-4-en-1-yn-3-yl] 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;EMPENTHRIN;ma108;-methyl-2-pentenylester;s2852;s2852f
CAS:54406-48-3
MF:C18H26O2
MW:274.4
EINECS:259-154-4
Product Categories:INSECTICIDE
Mol File:54406-48-3.mol
Empenthrin Structure
Empenthrin Chemical Properties
Melting point 25°C
Boiling point 377.38°C (rough estimate)
density 0.9965 (rough estimate)
vapor pressure 1.4×10-2 Pa (23.6 °C)
refractive index 1.5510 (estimate)
storage temp. 2-8°C
Water Solubility 0.11 mg l-1 (25 °C)
Stability:Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference54406-48-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xn;N,N,Xn
Risk Statements 22-51/53
Safety Statements 61
RIDADR UN 3082
RTECS GZ1728000
HS Code 29162090
MSDS Information
Empenthrin Usage And Synthesis
Chemical Propertiesliquid
UsesEmpenthrin is used as a domestic insecticide, especially against moths and other insects which attack fabrics.
UsesEmpenthrin is an insecticidal pyrethroid compound.
DefinitionChEBI: Empenthrin is a monoterpenoid.
Metabolic pathwayEmpenthrin is a low molecular weight ester of (1R)-chrysanthemic acid (2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylic acid). It has a relatively high vapour pressure and, unlike most pyrethroids, it is effective against flying insects. The molecule has three chiral centres and geometric isomerism in the alcohol group but, with the exception of the 1R acid, the full isomer mixture is used. As the insecticide has been developed for domestic use, it is unlikely that there will be a requirement for metabolism studies in plants or for extensive environmental fate studies. Its metabolism in rats has been reported, with particular attention paid to the fate of the novel alcohol moiety. As with other pyrethroids, ester cleavage and oxidation and conjugation of the alcohol metabolite predominated. The fate of the chrysanthemic acids can be assessed by reference to phenothrin.
DegradationEmpenthrin is a stable molecule but it would be expected to be labile at pH values above 10.
Empenthrin Dacthal (1,3,4,5,6,7-Hexahydro-1,3-dioxo-2H-isoindol-2-yl)methyl (1R-trans)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate Dimethyl sulfone Bensulfuron methyl Imiprothrin chlorempenthrin :(S)-2-Methyl-3-(2-propynyl)-4-oxocyclopent-2-enyl-(lR)-cis,trans-2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate Kresoxim-methyl Dimethyl sebacate Cyclopropanecarboxylic acid Methyl acrylate Dimethyl ether N,N-Dimethylacetamide Methyl bromide Cyphenothrin METHYL THIOPHENE-2-CARBOXYLATE Dimethyl sulfate

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