Magnesium dioxide

Magnesium dioxide Basic information
Product Name:Magnesium dioxide
Synonyms:Magnesium dioxide;MAGNESIUM PEROXIDE LIGHT;MAGNESII PEROXIDUM;magnesiumperoxide(mg(o2));MAGNESIUM PEROXIDE LIGHT, PH HELV;Magnesium peroxide light, Ph Eur;MAGNESIUM PEROXIDE FOR ANALYTICAL PURPOSE 24-28 % AS MGO2;24-28%asMgO2
CAS:14452-57-4
MF:MgO2
MW:56.3
EINECS:238-438-1
Product Categories:Oxidation;Peroxides;Synthetic Reagents
Mol File:14452-57-4.mol
Magnesium dioxide Structure
Magnesium dioxide Chemical Properties
solubility Practically insoluble in water and in ethanol (96 per cent). It dissolves in dilute mineral acids.
Merck 13,5704
LogP-0.425 (est)
CAS DataBase Reference14452-57-4
EPA Substance Registry SystemMagnesium peroxide (Mg(O2)) (14452-57-4)
Safety Information
Hazard Codes O,C
Risk Statements 8-34
Safety Statements 17-36-45-36/37/39-27-26
RIDADR UN 1476 5.1/PG 2
WGK Germany 3
Hazardous Substances Data14452-57-4(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
Magnesium dioxide Usage And Synthesis
Chemical PropertiesWhite or slightly yellow, amorphous, light powder.
Chemical PropertiesMagnesium peroxide is a white, odorless crystalline solid.
UsesMagnesium peroxide is used mainly in medicine for treating hyperacidity in the gastric intestinal tract, and in the treatment of metabolic diseases such as diabetes and ketonuria. It is also used in the preparation of toothpaste and antiseptic ointments. All of these uses involve a mixture of magnesium peroxide, magnesium oxide, magnesium hydroxide, and an admixture of magnesium carbonate. Magnesium peroxide is also used in bleaching and agricultural applications.
UsesBleaching and oxidizing agent, medicine (antacid).
General DescriptionA white powder. Noncombustible but accelerates the burning of combustible material, if the combustible material is finely divided the mixture may be explosive. Mixtures of combustible material and the peroxide can be ignited by friction or contact with moisture. Used in medicine, and as a bleaching agent.
Air & Water ReactionsInsoluble in water and slowly decomposed by water, liberating oxygen.
Reactivity ProfileMixtures of combustible material and the peroxide can be ignited with friction or moisture [AAR 1991]. Water gradually decomposes Magnesium dioxide liberating oxygen, with dilute acids Magnesium dioxide forms hydrogen peroxide, when strongly heated Magnesium dioxide losses all peroxide oxygen [Merck 11th ed. 1989].
HazardPowerful oxidizer and dangerous fire risk, reacts with acidic materials and moisture.
Health HazardInhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.
Fire HazardThese substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.
Safety ProfileA powerful oxidizer. Probably a severe irritant to the eyes, skin, and mucous membranes. Flammable by chemical reaction with acidic materials and moisture; an oxidizing agent. Dangerous; reacts vigorously with reducing agents; will decompose violently in or near a fire. See also MAGNESIUM COMPOUNDS and PEROXIDES, INORGANIC.
Potential ExposureMagnesium peroxide is used as a bleaching and oxidizing agent, and in the manufacture of antacids and antiinfective drugs.
ShippingUN1476 Magnesium peroxide, Hazard Class: 5.1; Labels: 5.1-Oxidizer.
IncompatibilitiesPowerful oxidizer. Dangerous fire risk with flammable and combustible materials. Violent reaction with acids. Keep away from moisture; causes the release of oxygen and heat.
Magnesium dioxide Preparation Products And Raw materials
Iron oxide Iron Oxide Black FERROUS SULFATE calcium bicarbonate Phosphorus pentoxide Barium sulfate Magnesium dioxide Magnesium hydroxide Hydrogen peroxide Magnesium stearate CARBON DIOXIDE Magnesium peroxide Rutile Magnesium oxide Magnesium sulfate Magnesium Magnesium sulfate heptahydrate

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