Ammonium citrate dibasic

Ammonium citrate dibasic Basic information
Product Name:Ammonium citrate dibasic
Synonyms:CITRIC ACID AMMONIUM SALT;CITRIC ACID, AMMONIUM SALT, DIBASIC;CITRIC ACID, DIAMMONIUM;CITRIC ACID, DIAMMONIUM, DIBASIC;CITRIC ACID DIAMMONIUM SALT;CITRIC ACID TRIAMMONIUM SALT;DI-AMMONIUM HYDROGEN CITRATE;AMMONIUM CITRATE
CAS:3012-65-5
MF:C6H14N2O7
MW:226.18
EINECS:221-146-3
Product Categories:Nutritional fortification substances
Mol File:3012-65-5.mol
Ammonium citrate dibasic Structure
Ammonium citrate dibasic Chemical Properties
Melting point 185 °C (dec.)(lit.)
Boiling point 100 °C(lit.)
density 1.22 g/mL at 20 °C
vapor density 1.8 (vs air)
refractive index 1.4650 (estimate)
storage temp. Store at +5°C to +30°C.
solubility H2O: 1 M at 20 °C, clear, colorless
form Solid
color White
OdorSlight ammonia odor
PH5.48(1 mM solution);5.29(10 mM solution);5.04(100 mM solution);6.16(1000 mM solution)
PH Range5.2
Water Solubility Soluble in water. Slightiy soluble in alcohol.
λmaxλ: 260 nm Amax: ≤0.05
λ: 280 nm Amax: ≤0.03
Merck 14,512
BRN 4925760
Stability:Stable.
InChIKeyYXVFQADLFFNVDS-UHFFFAOYSA-N
LogP-2.840
CAS DataBase Reference3012-65-5(CAS DataBase Reference)
EPA Substance Registry SystemDiammonium citrate (3012-65-5)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-36/37
Safety Statements 26-36
RIDADR UN 9087
WGK Germany 3
RTECS GE7545000
8
TSCA Yes
HS Code 29181500
Hazardous Substances Data3012-65-5(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Ammonium citrate dibasic Usage And Synthesis
Chemical Propertieswhite crystalline powder
Chemical PropertiesAmmonium citrate (various forms) is a white powdery material with a slight ammonia-like odor.
UsesAmmonium citrate dibasic is generally used as a component of matrix solution in matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectrometry analysis. It can also be used as both the carbon and nitrogen source to synthesize fluorescent nitrogen-doped carbon nanoparticles (CNPs).
UsesDetermination of phosphates.
UsesFor the determination of phosphate, especially in fertilizers.
UsesAmmonium Citrate, Dibasic is a flavor enhancer and ph control agent. it is the diammonium salt of citric acid, being prepared by partially neutralizing citric acid with ammonia. it is used in nonal- coholic beverages and certain cheeses.
DefinitionChEBI: A citrate salt in which two of the three carboxy groups are deprotonated and associated with ammonium ions as counter-cations.
General DescriptionAmmonium citrate is a white granular solid. Ammonium citrate dibasic is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Ammonium citrate dibasic is used in pharmaceuticals, and in chemical analysis.
Air & Water ReactionsWater soluble.
Reactivity ProfileSalts, basic, such as AMMONIUM CITRATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.
Health HazardInhalation causes respiratory irritation. Ingestion causes diarrhea. Contact with eyes causes mild irritation.
Fire HazardSpecial Hazards of Combustion Products: Toxic ammonia gas may form in fire.
Potential ExposureIt is used to make pharmaceuticals; rust-proofing compounds and plasticizers; as a food additive; stabilizing agent.
ShippingUN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
IncompatibilitiesContact with strong caustics causes the release of ammonia gas.
Waste DisposalMay be flushed to sewer with large volumes of water.
Ammonium citrate dibasic Preparation Products And Raw materials
Raw materialsAmmonia-->Citric acid
Sodium citrate CITRATE Ammonium phosphate dibasic AMMONIUM Diammonium glycyrrhizinate Ammonium nitrate DISODIUM HYDROGEN CITRATE SESQUIHYDRATE Ammonium dihydrogen phosphate Zinc citrate Hydrogen Ammonium citrate tribasic Ammonium acetate Molybdic acid Dimethyl succinate Sildenafil citrate 2-[5-(4-Chlorophenyl)pentyl]oxirane-2-carboxylic acid Ammonium sulfate Citric acid

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