DIETHYL VINYLPHOSPHONATE

DIETHYL VINYLPHOSPHONATE Basic information

Product Name:	DIETHYL VINYLPHOSPHONATE
Synonyms:	vinyl-phosphonicacidiethylester;Diethylvinylphosphonate, 98+ %;Diethylvinylphosphonate,97%;Diethyl ethenylphosphonate;Ethenylphosphonic acid diethyl ester;1-diethoxyphosphorylethene;Diethyl vinylphosphonate, 97% 10GR;O,O-Diethyl vinylphosphonate
CAS:	682-30-4
MF:	C6H13O3P
MW:	164.14
EINECS:	211-663-2
Product Categories:	Building Blocks;Chemical Synthesis;Organic Building Blocks;Phosphorus Compounds;Organic Building Blocks;Phosphonates/Phosphinates;Phosphorus Compounds
Mol File:	682-30-4.mol

DIETHYL VINYLPHOSPHONATE Chemical Properties

Boiling point	202 °C(lit.)
density	1.068 g/mL at 25 °C(lit.)
refractive index	n20/D 1.429(lit.)
Fp	>230 °F
storage temp.	2-8°C
form	Liquid
color	Clear colorless to light yellow
Specific Gravity	1.068
BRN	507596
CAS DataBase Reference	682-30-4

Safety Information

Hazard Codes	T
Safety Statements	23-24/25
RIDADR	UN3278
WGK Germany	3
RTECS	TA1150000
F	10
Hazard Note	Toxic
HazardClass	6.1
PackingGroup	III
HS Code	29319090

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

DIETHYL VINYLPHOSPHONATE Usage And Synthesis

Chemical Properties

clear colorless to light yellow liquid

Uses

Diethyl vinylphosphonate (DEVP) can be used as a precursor for the synthesis of:

α, β-unsaturated phosphonates by reacting with arylboronic acids via Pd-catalyzed Mizoroki?Heck reaction.
2-(arylamino)ethyl phosphonates by condensing with primary and secondary amines via the aza-Michael addition reaction.

It can be also employed as a monomer unit for the preparation of high-molecular-weight polymer, poly(diethyl vinylphosphonate)?using lanthanide complexes.{18)

DIETHYL VINYLPHOSPHONATE Preparation Products And Raw materials

Raw materials	Phosphonic acid, (2-bromoethyl)-, bis(trimethylsilyl) ester-->Phosphonic acid, [1-(methylseleno)ethyl]-, diethyl ester-->DIETHYL (2-CHLOROETHYL)PHOSPHONATE-->DIETHYLPHOSPHONOACETIC ACID-->DIETHYL 2-BROMOETHYLPHOSPHONATE-->Diethyl phosphite-->Trimethylsilyl cyanide-->Vinylphosphonic acid-->Ethanol-->Formaldehyde-->Vinyl bromide-->TETRAETHYL METHYLENEDIPHOSPHONATE
Preparation Products	TRIETHYL 4-PHOSPHONOCROTONATE-->TETRAETHYL ETHYLENEDIPHOSPHONATE

BIS(CHLOROPROPYL)PROPENYL-2-PHOSPHONATE TETRAISOPROPYL VINYLIDENE DIPHOSPHONATE DIETHYL 3,3-DIMETHYLCYCLOPENT-1-ENYLPHOSPHONATE (4-AMINO-3-PHENYL-2-THIOXO-2,3-DIHYDRO-THIAZOL-5-YL)-PHOSPHONIC ACID DIETHYL ESTER DIETHYL CYCLOHEXYLAMINOVINYL PHOSPHATE DIETHYL 3,3-DIMETHYLCYCLOHEX-1-ENYLPHOSPHONATE AURORA KA-1472 NIP 101 DIETHYL 3-METHYLCYCLOHEX-1-ENYLPHOSPHONATE DIETHYL ALLYLPHOSPHONATE AURORA KA-1473 DIETHYL DICHLOROVINYLPHOSPHONATE DIETHYL 3-METHYLCYCLOPENT-1-ENYLPHOSPHONATE AURORA KA-1442 DIETHYL 3-BROMO-1-PROPENE PHOSPHONATE DIETHYL PHOSPHATE AURORA KA-1458 AURORA KA-1444

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DIETHYL VINYLPHOSPHONATE

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