Furfuryl acetate

Furfuryl acetate Basic information
Description References
Product Name:Furfuryl acetate
Synonyms:FEMA 2490;FURFURYL ACETATE;2-(ACETOXYMETHYL)FURAN;2-furanmethanol acetate;2-FURANMETHYL ACETATE;ACETIC ACID FURFURYL ESTER;2-furfurylacetate;2-Furfuryl-acetate
CAS:623-17-6
MF:C7H8O3
MW:140.14
EINECS:210-775-9
Product Categories:Furans, Benzofurans & Dihydrobenzofurans;Alphabetical Listings;E-F;Flavors and Fragrances;Certified Natural ProductsFlavors and Fragrances;Building Blocks;Heterocycles;Furans, Benzofurans & Dihydrobenzofurans;ester Flavor;Furans;Heterocyclic Building Blocks;bc0001
Mol File:623-17-6.mol
Furfuryl acetate Structure
Furfuryl acetate Chemical Properties
Boiling point 175-177 °C(lit.)
density 1.118 g/mL at 25 °C(lit.)
FEMA 2490 | FURFURYL ACETATE
refractive index n20/D 1.462(lit.)
Fp 150 °F
storage temp. 2-8°C
form clear liquid
color colorless
Odorat 100.00 %. sweet fruity banana horseradish
Odor Typefruity
Water Solubility 0.5-1.0 g/100 mL at 23 ºC
JECFA Number739
BRN 116128
LogP1.09
CAS DataBase Reference623-17-6(CAS DataBase Reference)
NIST Chemistry Reference2-Furanmethanol, acetate(623-17-6)
EPA Substance Registry System2-Furanmethanol acetate (623-17-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 24/25-37/39-26
WGK Germany 3
RTECS LU9120000
Hazard Note Irritant
TSCA Yes
HS Code 29321900
MSDS Information
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Furfuryl acetate English
SigmaAldrich English
ACROS English
ALFA English
Furfuryl acetate Usage And Synthesis
DescriptionFurfuryl acetate is the ester formed by the esterification between furfuryl alcohol and acetate. It can be used as a food spices and flavoring ingredient. It can also be used as the intermediate of dye, resin and spices. It is found in alcoholic beverage. Furfuryl acetate is present in wheat bread, crisp bread, roasted onion, pork liver, beer, rum, cocoa and coffee.
ReferencesKim, You Sun, S. S. Lee, and M. W. Oh. "Halogen Containing Heterocyclic Compounds (Part III) Chlorination of Furfuryl Acetate in Presence of Acid and Lewis Acids." Soil Biology & Biochemistry 924.1(1970):263-270.
Harayama, Koichi, F. Hayase, and H. Kato. "Contribution to Stale Flavor of 2-Furfuryl Ethyl Ether and Its Formation Mechanism in Beer." Bioscience Biotechnology & Biochemistry 59.6(1995):1144-1146.
Antón, Víctor, et al. "Thermophysical Characterization of Furfuryl Esters: Experimental and Modeling." Energy & Fuels (2017).

Chemical PropertiesFurfuryl acetate is a colorless to light yellow liquid with a ethereal foral fruity odor.
OccurrenceReported found in roasted almonds, beer, white bread, cocoa, coffee, roasted flberts, roasted onion, roasted peanuts, cooked pork liver, wheaten and crispbread, oats, rum, beer, licorice, dried bonito, sukiyaki and Bourbon vanilla
UsesFurfuryl acetate is a flavoring ingredient. It was used in the synthesis of 5-acetoxymethyl-2-vinylfuran and 5-hydroxymethyl-2-vinylfuran via Vilsmeier-Haack and Wittig reactions.
DefinitionChEBI: Furfuryl acetate is a heteroarene.
General DescriptionColorless to clear yellow or orange liquid with a pungent odor.
Air & Water ReactionsSlightly water soluble.
Reactivity ProfileFurfuryl acetate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Furfuryl acetate reacts with strong oxidizing agents, strong acids, strong bases and strong reducing agents. Furfuryl acetate reacts violently with cyanoacetic acid, formic acid, mineral acids, nitric acid and (nitric acid + N204 + sulfuric acid).
Fire HazardFurfuryl acetate is combustible.
Furfuryl acetate Tocopheryl acetate FURFURYL ACRYLATE Sodium acetate FURFURYL METHACRYLATE POLY(VINYL ACETATE) Cellulose acetate METHYL 3-(5-([(4-CHLOROBENZOYL)OXY]METHYL)-2-FURYL)-2-THIOPHENECARBOXYLATE 5-Nitro-2-furaldehyde diacetate ACETATE Amyl acetate Ethyl acetate Glatiramer acetate Triacetin Vinyl acetate Furfuryl alcohol Benzyl acetate Ammonium acetate

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